Art

J-GLOBAL ID：200902220678344836   Reference number：09A1237202

SmI₂-induced cyclization of optically active (E)- and (Z)-β-alkoxyvinyl sulfoxides with aldehydes

アルデヒドを含む光学活性な(E)-および(Z)-β-アルコキシビニルスルホキシド類のSmI₂に誘発される環化

Author (3)： KIMURA Tomohiro (Dep. of Chemistry, Fac. of Sci., Tokyo Univ. of Sci., 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, JPN) ,  HAGIWARA Mayumi (Dep. of Chemistry, Fac. of Sci., Tokyo Univ. of Sci., 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, JPN) ,  NAKATA Tadashi (Dep. of Chemistry, Fac. of Sci., Tokyo Univ. of Sci., 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 65  Issue： 52  Page： 10893-10900  Publication year： Dec. 26, 2009 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *sulfoxide ,  enol ether ,  *aldehyde ,  *cyclization reaction ,  radical reaction ,  samarium compound ,  iodide ,  asymmetric synthesis ,  regiospecific reaction ,  reaction mechanism
Semi thesaurus term： samarium diiodide

JST classification (2)： Aromatic monocyclic sulfoxides,sulfones,sulfonium compounds  (CF05130Q) ,  Photochemical reaction,radical reaction  (CF02090A)

Substance index (5)： (2R,4aα,8aβ)-2α-Phenyl-7α-[[(E)-2-(4-methylphenylsulfinyl)ethenyl]oxy]hexahydropyrano[3,2-d]-1,3-dioxin-6β-acetaldehyde ,  (2S,3R,5S,6R,8S,9R)-1-(4-Methylphenylsulfinyl)-3-acetoxy-8,10-[[(R)-benzylidene]bisoxy]-2,6:5,9-diepoxydecane ,  (2R,4aα,8aβ)-2α-Phenyl-7α-[[(Z)-2-(4-methylphenylsulfinyl)ethenyl]oxy]hexahydropyrano[3,2-d]-1,3-dioxin-6β-acetaldehyde ,  (2R,4aα,8aβ,9aβ,10aα)-2α-Phenyl-6β-acetoxy-7α-(4-methylphenylsulfinylmethyl)octahydro-2H,5H-1,3,8,10-tetraoxaanthracene ,  (2R,4aα,8aβ)-2α-Phenyl-6β-[(2S,3E)-2-acetoxy-4-(4-methylphenylsulfinyl)-3-butenyl]-7α-acetoxyhexahydropyrano[3,2-d]-1,3-dioxin

Terms in the title (4)： アルデヒド ,  光学活性 ,  誘発 ,  環化