Art

J-GLOBAL ID：200902221495093210   Reference number：04A0462697

Origin of Regioselectivity in Photocycloaddition Reactions of 2-Cyclohexenone with Cycloalkenecarboxylates

2-シクロヘキセノンとシクロアルケンカルボキシラートの光環状付加反応の位置選択性の起源

Author (4)： ODO Y (Kagoshima Univ., Kagoshima) ,  SHIMO T (Kagoshima Univ., Kagoshima) ,  HORI K (Yamaguchi Univ., Ube) ,  SOMEKAWA K (Kagoshima Univ., Kagoshima)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 77  Issue： 6  Page： 1209-1215  Publication year： Jun. 15, 2004 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *enone ,...

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JST classification (4)： Addition reaction,elimination reaction  (CF02030M) ,  Photochemical reactions  (CB08020F) ,  Electronic structure of molecules  (BH05010Q) ,  Cyclohexanes  (CF04050W)

Substance index (8)： 3-Methyl-2-cyclohexen-1-one ,  1-Cyclohexene-1-carboxylic acid methyl ,  Methyl 1-cyclopentene-1-carboxylate ,  1-Cyclobutene-1-carboxylic acid methyl ester ,  (2β,8α)-3-Oxo-7β-methyltricyclo[6.2.0.0^2,7]decane-1α-carboxylic acid methyl ester ,  (2β,8α)-3-Oxo-7β-methyltricyclo[6.3.0.0^2,7]undecane-1α-carboxylic acid methyl ester ,  (7α,8β)-2α-Methyl-6-oxotricyclo[6.3.0.0^2,7]undecane-1β-carboxylic acid methyl ester ,  (7α,8β)-2α-Methyl-6-oxotricyclo[6.4.0.0^2,7]dodecane-1β-carboxylic acid methyl ester

Reference (29)：

• 1) a) M. Demuth and G. Mikhail, Synthesis, 1989, 145.
•  b) D. D. Keukeleire and S.-L. He, Chem. Rev., 93, 145 (1993).
• 2) I. Fleming, “Frontier Orbitals and Organic Chemical Reactions,” John Wiley & Sons Ltd., London, Great Britain (1976), Chap. 6.
• 3) a) D. I. Schuster, G. Lem, and N. A. Kaprinidis, Chem. Rev., 93, 3 (1993).
•  b) D. I. Schuster, “CRC Handbook of Organic Photochemistry and Photobiology,” ed by W. Horspool and F. Lenci, CRC Press, London (2003), pp. 72-1–72-24.

Terms in the title (3)： 光環状付加 ,  位置選択性 ,  起源