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J-GLOBAL ID：200902221700336083   Reference number：05A0569454

Reactions of guaiazulene with methyl terephthalaldehydate and 2-hydroxy- and 4-hydroxybenzaldehydes in methanol in the presence of hexafluorophosphoric acid: comparative studies on molecular structures and spectroscopic, chemical and electrochemical properties of monocarbocations stabilized by 3-guaiazulenyl and phenyl groups

ヘキサフルオロりん酸の存在下のメタノール中のグアイアズレンとテレフタルアルデヒド酸メチル及び2-ヒドロキシ-及び4-ヒドロキシベンズアルデヒドとの反応 3-グアイアズレニル及びフェニル基によって安定化したモノカルボカチオンの分子構造及び分光学的,化学的及び電気化学的特性についての比較研究

Author (7)： TAKEKUMA Shin-ichi (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ., Osaka, JPN) ,  HATA Yasuhito (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ., Osaka, JPN) ,  NISHIMOTO Toyosato (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ., Osaka, JPN) ,  NOMURA Eiko (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ., Osaka, JPN) ,  SASAKI Masato (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ., Osaka, JPN) ,  MINEMATSU Toshie (School of Pharmaceutical Sci.s, Kinki Univ., 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JPN) ,  TAKEKUMA Hideko (Dep. of Applied Chemistry, Fac. of Sci. and Engineering, Kinki Univ., Osaka, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 61  Issue： 28  Page： 6892-6907  Publication year： Jul. 11, 2005 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： fluorophosphoric acid ,...

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JST classification (2)： Monoterpenes,sesquiterpenes  (CF10022A) ,  Aromatic monocyclic aldehydes  (CF05160X)

Substance index (18)： Methanol ,  Salicylaldehyde ,  4-Hydroxybenzaldehyde ,  Guaiazulene ,  4-Formylbenzoic acid methyl ,  Terephthalaldehyde ,  [4-(Methoxycarbonyl)phenyl](3,8-dimethyl-5-isopropylazulene-1-yl)methylium・hexafluorophosphate ,  (4-Hydroxyphenyl)(3,8-dimethyl-5-isopropylazulene-1-yl)methylium・hexafluorophosphate ,  (3-Hydroxyphenyl)(3,8-dimethyl-5-isopropylazulene-1-yl)methylium・hexafluorophosphate ,  4,4′-[(1S,2R)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bis(benzoic acid methyl) ester ,  4,4′-[(1R,2R)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bis(benzoic acid methyl) ester ,  2,2′-[(1S,2R)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bisphenol ,  2,2′-[(1R,2R)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bisphenol ,  4,4′-[(1S,2R)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bisphenol ,  4,4′-[(1R,2R)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bisphenol ,  4,4′-[(1S,2S)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bis(benzoic acid methyl) ester ,  2,2′-[(1S,2S)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bisphenol ,  4,4′-[(1S,2S)-1,2-Bis(3,8-dimethyl-5-isopropylazulene-1-yl)ethylene]bisphenol

Terms in the title (12)： フルオロりん酸 ,  メタノール ,  グアイアズレン ,  テレフタルアルデヒド酸メチル ,  4-ヒドロキシベンズアルデヒド ,  フェニル基 ,  カルボカチオン ,  分子構造 ,  分光学 ,  化学 ,  電気化学的特性 ,  研究