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J-GLOBAL ID：200902222955093571   Reference number：06A0128217

Convenient synthesis of highly optically active 2,3,4,6-tetrasubstituted tetrahydropyrans via Prins cyclization reaction (PCR) of optically active homoallylic alcohols with aldehydes

光学活性ホモアリル性アルコールとアルデヒドのPrins環化反応(PCR)を経由する高光学活性2,3,4,6-テトラ置換テトラヒドロピラン類の簡易合成

Author (4)： KATAOKA Kazuhide (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1 Ridai-cho, Okayama 700-0005, JPN) ,  ODE Yosuke (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1 Ridai-cho, Okayama 700-0005, JPN) ,  MATSUMOTO Masashi (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1 Ridai-cho, Okayama 700-0005, JPN) ,  NOKAMI Junzo (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1 Ridai-cho, Okayama 700-0005, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 62  Issue： 11  Page： 2471-2483  Publication year： Mar. 13, 2006 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： aldehyde ,...
Semi thesaurus term： Prins環化反応

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JST classification (4)： Alkenes  (CF03030T) ,  Aliphatic aldehydes  (CF03180F) ,  Pyranes  (CF07092R) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (13)： 3-Phenylpropanal ,  Benzaldehyde ,  Cinnamaldehyde ,  (R,E)-1-Phenyl-5-heptene-3-ol ,  (2S)-2β,6β-Diphenethyl-3α-methyl-4β-acetoxytetrahydro-2H-pyran ,  (2S)-2β-[5-(Benzyloxy)pentyl]-3α-methyl-4β-acetoxy-6β-phenethyltetrahydro-2H-pyran ,  (2S)-2β-Styryl-3α-methyl-4β-acetoxy-6β-phenethyltetrahydro-2H-pyran ,  (3R,5Z)-1-Phenyl-5-heptene-3-ol ,  (2R)-2α,6α-Diphenethyl-3α-methyl-4α-acetoxytetrahydro-2H-pyran ,  (2S)-2β,6β-Diphenethyl-3α-methyl-4β-fluorotetrahydro-2H-pyran ,  (2S)-2β-Pentyl-3α-methyl-4β-fluoro-6β-phenethyltetrahydro-2H-pyran ,  (2S)-2β,6β-Diphenethyl-3α-methyl-4β-chlorotetrahydro-2H-pyran ,  (2S)-2β,6β-Diphenethyl-3α-methyl-4β-(tosyloxy)tetrahydro-2H-pyran

Terms in the title (11)： 光学活性 ,  ホモ ,  アリル ,  アルコール ,  アルデヒド ,  Prins環化 ,  PCR ,  テトラ ,  置換 ,  テトラヒドロピラン類 ,  簡易