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J-GLOBAL ID：200902223574121346   Reference number：05A0549595

Synthesis of a 4,5-epoxy-2-cyclohexen-1-one derivative via epoxide ring opening, 1,3-carbonyl transposition and epoxide ring regeneration: a synthetic study on a scyphostatin analogue

エポキシドの開環,1,3-カルボニル位置移動およびエポキシド環の再生を経由しての4,5-エポキシ-2-シクロヘキセン-1-オン誘導体の合成 シホスタチン類似体の合成研究

Author (4)： TAKAGI Ryukichi (Hiroshima Univ., Higashi-Hiroshima, JPN) ,  TOJO Kengo (Hiroshima Univ., Higashi-Hiroshima, JPN) ,  IWATA Masato (Hiroshima Univ., Higashi-Hiroshima, JPN) ,  OHKATA Katsuo (Hiroshima Univ., Higashi-Hiroshima, JPN)
Material： Organic & Biomolecular Chemistry  (Org Biomol Chem)
Volume： 3  Issue： 10  Page： 2031-2036  Publication year： May. 21, 2005 
JST Material Number： A0499C  ISSN： 1477-0520  CODEN： OBCRAK  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Three-membered heterocyclic compounds  (CF07050R) ,  Basic research of enzyme preparations and enzyme inhibitor preparations  (GW21010W)

Substance index (11)： Scyphostatin ,  (1S,6S)-2α-Hydroxy-2-[(S)-2-amino-3-hydroxypropyl]-7-oxabicyclo[4.1.0]hepta-4-ene-3-one ,  N-[(1aS,2R)-5′,7-Dioxo-2aβ,3,4′,6,6aβ,7aβ-hexahydro-3β,6β-methanospiro[naphtho[2,3-b]oxirene-2(1aβH),2′(3′H)-furan]-4′α-yl]carbamic acid benzyl ester ,  (1R,6R)-2α-Hydroxy-2-(3-hydroxypropyl)-7-oxabicyclo[4.1.0]hepta-4-ene-3-one ,  (1aR,2R)-2aβ,3,6,6aβ-Tetrahydro-3β,6β-methanospiro[naphtho[2,3-b]oxirene-2(1aαH),2′(3′H)-furan]-5′,7(4′H,7aαH)-dione ,  (5R)-10β-(Triethylsiloxy)-1-oxaspiro[4.5]deca-6-ene-2,8-dione ,  (1α,2R,6α)-3α-(Triethylsiloxy)-7-oxaspiro[bicyclo[4.1.0]heptane-2,2′-oxolane]-5,5′-dione ,  (5R)-6α-Hydroxy-10β-(triethylsiloxy)-1-oxaspiro[4.5]deca-7-ene-2-one ,  Pivalic acid 3-[(1S)-1α-hydroxy-2-oxo-6β-[(triethylsilyl)oxy]-3-cyclohexenyl]propyl ester ,  Pivalic acid 3-[(1S)-1α-hydroxy-2-oxo-5α-bromo-6β-[(triethylsilyl)oxy]-3-cyclohexenyl]propyl ester ,  (1R,2S,6R)-2-Hydroxy-2-[3-(pivaloyloxy)propyl]-7-oxabicyclo[4.1.0]hepta-4-ene-3-one

Terms in the title (9)： エポキシド ,  開環 ,  カルボニル ,  環 ,  2-シクロヘキセン-1-オン ,  誘導体 ,  シホスタチン ,  類似体 ,  研究