Art

J-GLOBAL ID：200902225302803742   Reference number：03A0175244

Stereoselective synthesis of 2-methylenepyrrolizidines by tandem cyclization of N-propargylaminyl radicals.

N-プロパルギルアミニルラジカルの逐次環化による2-メチレンピロリジジン類の立体選択的合成

Author (5)： HASEGAWA H (Hokkaido Univ., Sapporo, JPN) ,  SENBOKU H (Hokkaido Univ., Sapporo, JPN) ,  KAJIZUKA Y (Hokkaido Univ., Sapporo, JPN) ,  ORITO K (Hokkaido Univ., Sapporo, JPN) ,  TOKUDA M (Hokkaido Univ., Sapporo, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 59  Issue： 6  Page： 827-832  Publication year： Feb. 03, 2003 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *nitrogen heterocyclic compound ,...
Semi thesaurus term： aminyl radical

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JST classification (2)： Condensed derivatives of pyrroles  (CF07077C) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (18)： Propargylamine ,  Tributyltin ,  (E)-N-(2-Propynyl)-5-nonene-2-amine ,  (E)-N-(2-Propynyl)-6-phenyl-5-hexene-2-amine ,  (E)-N-(2-Propynyl)-1,5-diphenyl-4-pentene-1-amine ,  (E)-N-(2-Propynyl)-1-methyl-5-(triethylsilyl)-4-pentene-1-amine ,  (Z)-N-(2-Propynyl)-1-methyl-5-phenyl-4-pentene-1-amine ,  (1S,2S)-N-(2-Propynyl)-2-[(E)-3-phenyl-2-propenyl]cyclohexanamine ,  (1S,5S,7aR)-1-Propyl-2-methylene-5-methylhexahydro-1H-pyrrolizine ,  (1S,7aβ)-1β-Phenyl-2-methylene-5β-methylhexahydro-1H-pyrrolizine ,  (1S,5R,7aR)-1,5-Diphenyl-2-methylenehexahydro-1H-pyrrolizine ,  (1S,5S,7aR)-1-(Triethylsilyl)-2-methylene-5-methylhexahydro-1H-pyrrolizine ,  (1R,7aR)-1β-Phenyl-2β,5β-dimethyl-hexahydro-1H-pyrrolizine ,  (1R,7aR)-1β-Phenyl-2α,5β-dimethyl-hexahydro-1H-pyrrolizine ,  (E)-N-Allyl-6-phenyl-5-hexene-2-amine ,  (1S,4aS,8aS,9aR)-1-Phenyl-2-methylene-decahydro-1H-pyrrolo[1,2-a]indole ,  (1S,5S,7aR)-1-Propyl-2-(chloromethylene)-5-methylhexahydro-1H-pyrrolizine ,  (1S,5S,7aR)-1-Phenyl-2-(chloromethylene)-5-methylhexahydro-1H-pyrrolizine

Terms in the title (3)： 逐次 ,  環化 ,  立体選択的合成