Art

J-GLOBAL ID：200902225511163106   Reference number：09A0206585

ONE POT SYNTHESIS OF OPTICALLY ACTIVE 4-ISOXAZOLINES BY ASYMMETRIC ADDITION OF ALKYNYLZINC REAGENTS TO NITRONES FOLLOWED BY CYCLIZATION

ニトロン類へのアルキル亜鉛試薬の非対称添加引続いての環化による光学活性4-イソオキサゾリン類のワンポット合成

Author (4)： WEI Weilin (Kanazawa Univ., Ishikawa, JPN) ,  KOBAYASHI Masato (Kanazawa Univ., Ishikawa, JPN) ,  UKAJI Yutaka (Kanazawa Univ., Ishikawa, JPN) ,  INOMATA Katsuhiko (Kanazawa Univ., Ishikawa, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 78  Issue： 3  Page： 717-724  Publication year： Mar. 01, 2009 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： oxygen heterocyclic compound ,  nitrogen heterocyclic compound ,  one-pot synthesis ,  *cyclization reaction ,  nitrone ,  aromatic hydrocarbon ,  acetylenic compound ,  *Isoxazoles

JST classification (2)： Oxazoles,isoxazoles  (CF07080Y) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (18)： 4-Bromophenylacetylene ,  Dimethylzinc ,  Phenylacetylene ,  1-Hexyne ,  1-Octyne ,  2-O,3-O-Bis(methylzincio)-L-tartaric acid di-tert-butyl ester ,  Benzylbenzylideneamine N-oxide ,  N-(2-Bromobenzylidene)benzylamine oxide ,  N-(4-Bromobenzylidene)benzylamine oxide ,  (4-Pentylphenyl)acetylene ,  2-Benzyl-3α,5-diphenyl-4-isoxazoline ,  (3S)-2-Benzyl-3-(2-bromophenyl)-5-phenyl-4-isoxazoline ,  (3S)-2-Benzyl-3-(4-bromophenyl)-5-phenyl-4-isoxazoline ,  (3S)-2-Benzyl-3-phenyl-5-(4-pentylphenyl)-4-isoxazoline ,  (3S)-2-Benzyl-3-phenyl-5-(4-bromophenyl)-4-isoxazoline ,  (3S)-2-Benzyl-3-phenyl-5-butyl-4-isoxazoline ,  (3S)-2-Benzyl-3-phenyl-5-hexyl-4-isoxazoline ,  (3R)-2-Benzyl-3,5-diphenyl-4-isoxazoline-4-methanol

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Terms in the title (8)： ニトロン ,  亜鉛 ,  試薬 ,  非対称 ,  環化 ,  光学活性 ,  イソオキサゾリン類 ,  ワンポット合成