Art

J-GLOBAL ID：200902226145724201   Reference number：05A0868576

Stereoselective Cross-Coupling Reaction of 1,1-Diboryl-1-alkenes with Electrophiles: A Highly Stereocontrolled Approach to 1,1,2-Triaryl-1-alkenes

1,1-ジボリル-1-アルケンと求電子試薬との立体選択的交差カップリング反応: 1,1,2-トリアリール-1-アルケンへの高度に立体制御されたアプローチ

Author (6)： SHIMIZU Masaki (Kyoto Univ., Kyoto, JPN) ,  NAKAMAKI Chihiro (Kyoto Univ., Kyoto, JPN) ,  SHIMONO Katsuhiro (Kyoto Univ., Kyoto, JPN) ,  SCHELPER Michael (Kyoto Univ., Kyoto, JPN) ,  KURAHASHI Takuya (Kyoto Univ., Kyoto, JPN) ,  HIYAMA Tamejiro (Kyoto Univ., Kyoto, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 127  Issue： 36  Page： 12506-12507  Publication year： Sep. 14, 2005 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *cross coupling reaction ,...

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JST classification (2)： Organoboron compounds  (CF08020R) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (35)： 1,1-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-phenyl-1-butene ,  1,1-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-(4-methylphenyl)-1-butene ,  1,1-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-[4-(trifluoromethyl)phenyl]-1-butene ,  1,1-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-phenyl-1-propene ,  1,1-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-phenyl-3-methyl-1-butene ,  1,1-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-2-phenyl-3,3-dimethyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1,2-diphenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-fluorophenyl)-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-[4-(trifluoromethyl)phenyl]-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-[4-(ethoxycarbonyl)phenyl]-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-aminophenyl)-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-methoxyphenyl)-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-[4-[2-(dimethylamino)ethoxy]phenyl]-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-methylphenyl)-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(2-methylphenyl)-2-phenyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-fluorophenyl)-2-(4-methylphenyl)-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-fluorophenyl)-2-[4-(trifluoromethyl)phenyl]-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1,2-diphenyl-1-propene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-[4-(trifluoromethyl)phenyl]-2-phenyl-1-propene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-methoxyphenyl)-2-phenyl-1-propene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-[4-(trifluoromethyl)phenyl]-2-phenyl-3-methyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-methoxyphenyl)-2-phenyl-3-methyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-[4-(trifluoromethyl)phenyl]-2-phenyl-3,3-dimethyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1-(4-methoxyphenyl)-2-phenyl-3,3-dimethyl-1-butene ,  1-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-1,2-diphenyl-3,3,3-trifluoro-1-propene ,  1-[4-(2-Dimethylaminoethoxy)phenyl]-1,2-diphenyl-1-butene ,  1-(4-Methoxyphenyl)-1-(4-fluorophenyl)-2-phenyl-1-butene ,  1-[4-(Trifluoromethyl)phenyl]-1-(4-methoxyphenyl)-2-phenyl-1-butene ,  1-(4-Methylphenyl)-1-(4-methoxyphenyl)-2-phenyl-1-butene ,  1-(4-Methylphenyl)-1,2-diphenyl-1-butene ,  cis-Tamoxifen ,  (1E,3E)-1,4-Diphenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1,3-hexadiene ,  (1Z,3E)-1,4-Diphenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-1,3-hexadiene ,  (3Z,5E)-3-Phenyl-4-[(E)-styryl]-3,5-undecadiene ,  (1E,3Z)-1,3,4-Triphenyl-1,3-hexadiene

Terms in the title (5)： アルケン ,  求電子試薬 ,  立体 ,  交差カップリング反応 ,  立体制御