Art

J-GLOBAL ID：200902226586883372   Reference number：08A0080459

Copper-Catalyzed Intermolecular Generation of Ammonium Ylides with Subsequent [2,3]Sigmatropic Rearrangement. Efficient Synthesis of Bifunctional Homoallylamines

銅触媒によるアンモニウムイリドの分子間発生に続く[2,3]シグマトロピー転位 二官能性ホモアリルアミンの効率的合成

Author (5)： HONDA Kiyoshi (Graduate School of Engineering, Yokohama National Univ.) ,  SHIBUYA Hiromasa (Graduate School of Engineering, Yokohama National Univ.) ,  YASUI Hiroto (Graduate School of Engineering, Yokohama National Univ.) ,  HOSHINO Yujiro (Graduate School of Environment and Information Scieneces, Yokohama National Univ.) ,  INOUE Seiichi (Graduate School of Environment and Information Scieneces, Yokohama National Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 81  Issue： 1  Page： 142-147 (J-STAGE)  Publication year： 2008 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *transition metal catalyst ,...
Semi thesaurus term： allylamine compound

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JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Amino acids  (CF10070V)

Substance index (15)： 1-(Benzyloxymethyl)-2-methylallyldimethylamine ,  1-[3-Methyl-5-(benzyloxy)-3-pentenyl]-2-methylallyldimethylamine ,  (Dimethylamino)(2-methyl-4-benzyloxy-2-butenyl)malonic acid diethyl ester ,  2-[8-(Benzyloxy)-2,6-dimethyl-2,6-octadienyl]-2-(dimethylamino)malonic acid diethyl ester ,  2-Phenyl-2-diazoacetic acid ethyl ester ,  2-Methylallyldimethylamine ,  2-Diazo-3-oxobutyric acid ethyl ,  N,N-Dimethyl-2-[4-(benzyloxy)-2-methyl-2-butenyl]-2-acetylglycine ethyl ester ,  N,N-Dimethyl-2-[4-(benzyloxy)-2-methyl-2-butenyl]-2-phenylglycine ethyl ester ,  N,N-Dimethyl-2-[8-(benzyloxy)-2,6-dimethyl-2,6-octadienyl]-2-phenylglycine ethyl ester ,  N,N-Dimethyl-2-allylglycine ethyl ester ,  N,N-Dimethyl-2-isopropenylglycine ethyl ester ,  N,N-Dimethylallylamine ,  2-Diazomalonic acid diethyl ,  Diazoacetic acid ethyl

Reference (48)：

• 1) a) D. J. Faulkner, Synthesis 1971, 175.
•  b) S. Inoue, K. Honda, J. Synth. Org. Chem., Jpn. 1993, 51, 894.
• 2) a) R. W. Hoffmann, Angew. Chem., Int. Ed. Engl. 1979, 18, 563.
•  b) T. Nakai, K. Mikami, Chem. Rev. 1986, 86, 885.
•  c) K. Mikami, T. Nakai, Synthesis 1991, 594.

Terms in the title (6)： 銅触媒 ,  アンモニウムイリド ,  シグマトロピー転位 ,  二官能性 ,  ホモ ,  アリルアミン