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J-GLOBAL ID：200902231737550064   Reference number：04A0625911

An enantioselective synthesis of phomopsolide D.

ホモプソリドDのエナンチオ選択的合成

Author (2)： LI M (West Virginia Univ., WV, USA) ,  O'DOHERTY G A (West Virginia Univ., WV, USA)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 45  Issue： 34  Page： 6407-6411  Publication year： Aug. 16, 2004 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric reaction ,...
Semi thesaurus term： dihydroxylation ,...

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JST classification (3)： Other natural substances of biological origin  (CF10090R) ,  Pyranes  (CF07092R) ,  Synthesis of antibiotics  (GX04000Z)

Substance index (19)： Phomopsolide C ,  Phomopsolide D ,  2,4-Hexadienal ,  2-Furyllithium ,  2-(1-Oxo-2,4-hexadienyl)furan ,  (4S,5S)-1-(2-Furanyl)-4,5-dihydroxy-2-hexene-1-one ,  (4S)-2,2,4β-Trimethyl-5α-[3-oxo-3-(2-furanyl)-1-propenyl]-1,3-dioxolane ,  (4S)-2,2,4β-Trimethyl-5α-[(3S)-3-hydroxy-3-(2-furanyl)propyl]-1,3-dioxolane ,  (4S)-2,2,4β-Trimethyl-5α-[(3R)-3-hydroxy-3-(2-furanyl)propyl]-1,3-dioxolane ,  (2S)-2β-[2-[(4S)-2,2,5α-Trimethyl-1,3-dioxolane-4β-yl]ethyl]-6-hydroxy-3,6-dihydro-2H-pyran-3-one ,  (6S)-6-[2-[(4S)-2,2,5α-Trimethyl-1,3-dioxolane-4β-yl]ethyl]-5,6-dihydro-2H-pyran-2,5-dione ,  (5S)-5α-Hydroxy-6α-[2-[(4S)-2,2,5α-trimethyl-1,3-dioxolane-4β-yl]ethyl]-5,6-dihydro-2H-pyran-2-one ,  (5R)-5β-Hydroxy-6α-[2-[(4S)-2,2,5α-trimethyl-1,3-dioxolane-4β-yl]ethyl]-5,6-dihydro-2H-pyran-2-one ,  (5S)-5α-[[(E)-2-Methyl-2-butenoyl]oxy]-6α-[2-[(4S)-2,2,5α-trimethyl-1,3-dioxolane-4β-yl]ethyl]-5,6-dihydro-2H-pyran-2-one ,  4-epi-Phomopsolide D ,  (5R)-5β-[[(E)-2-Methyl-2-butenoyl]oxy]-6α-[2-[(4S)-2,2,5α-trimethyl-1,3-dioxolane-4β-yl]ethyl]-5,6-dihydro-2H-pyran-2-one ,  (5S)-5α-[[(E)-2-Methyl-2-butenoyl]oxy]-6β-[2-[(4S)-2,2,5α-trimethyl-1,3-dioxolane-4β-yl]ethyl]-5,6-dihydro-2H-pyran-2-one ,  4,5-diepi-Phomopsolide D ,  5-epi-Phomopsolide D

Terms in the title (1)： エナンチオ選択的合成