Art

J-GLOBAL ID：200902232741790122   Reference number：08A1020439

Reaction Mechanisms of IO Radical Formation from the Reaction of CH₃I with Cl Atom in the Presence of O₂

O₂存在下でのCH₃IとCl原子との反応によるIOラジカル生成の反応機構

Author (7)： ENAMI Shinichi (Dep. of Molecular Engineering, Kyoto Univ.) ,  SAKAMOTO Yosuke (Dep. of Molecular Engineering, Kyoto Univ.) ,  YAMANAKA Takashi (Dep. of Molecular Engineering, Kyoto Univ.) ,  HASHIMOTO Satoshi (Dep. of Molecular Engineering, Kyoto Univ.) ,  KAWASAKI Masahiro (Dep. of Molecular Engineering, Kyoto Univ.) ,  TONOKURA Kenichi (Environmental Sci. Center, The Univ. of Tokyo) ,  TACHIKAWA Hiroto (Dep. of Materials Chemistry, Fac. of Engineering, Hokkaido Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 81  Issue： 10  Page： 1250-1257 (J-STAGE)  Publication year： 2008 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *aliphatic iodine compound ,  *chlorine ,  *atom ,  *oxygen ,  iodine oxide ,  radical ,  *reaction mechanism ,  intracavity laser spectroscopy ,  concentration dependence ,  partial pressure ,  pressure effect ,  temperature dependence ,  reaction rate constant ,  reaction product ,  branching ratio ,  computer simulation ,  *radical reaction ,  hydroxyl radical ,  nitrogen oxide
Semi thesaurus term： cavity ringdown spectroscopy ,  pressure dependence

JST classification (3)： Atomic reaction and radical reaction  (CB06030C) ,  Nonmetallic compounds  (CD01070R) ,  Aliphatic halogen compounds  (CF03050P)

Substance index (2)： Methyl iodide ,  Diiodomethane

Reference (51)：

• 1) R. von Glasow, P. J. Crutzen, in Tropospheric Halogen Chemistry in Treatise on Geochemistry, ed. by H. D. Holland, K. K. Turekian, 2007.
• 2) J. G. Calvert, S. E. Lindberg, Atmos. Environ. 2004, 38, 5087.
• 3) A. Saiz-Lopez, J. M. C. Plane, Geophys. Res. Lett. 2004, 31, L04112.
• 4) L. J. Carpenter, Chem. Rev. 2003, 103, 4953.
• 5) B. Alicke, K. Hebestreit, J. Stutz, U. Platt, Nature 1999, 397, 572.

Terms in the title (3)： O2 ,  Cl原子 ,  ラジカル生成