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J-GLOBAL ID：200902235053034127   Reference number：06A0954775

Asymmetric Syntheses of (-)-Mitorubrin and Related Azaphilone Natural Products

(-)-ミトルブリン及び関連アザフィロン天然物の不斉合成

Author (2)： ZHU Jianglong (Boston Univ., Massachusetts) ,  PORCO John A., Jr. (Boston Univ., Massachusetts)
Material： Organic Letters  (Org Lett)
Volume： 8  Issue： 22  Page： 5169-5171  Publication year： Oct. 26, 2006 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...
Semi thesaurus term： Ascomycetes

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JST classification (2)： Other natural substances of biological origin  (CF10090R) ,  Microorganism biochemistry  (EG03020N)

Substance index (14)： Mitorubrin ,  Mitorubrinol ,  (-)-Mitorubrinal ,  (-)-Mitorubrinic acid ,  2,4-Dihydroxy-3-methyl-6-bromobenzaldehyde ,  2,4-Dihydroxy-3-methyl-6-ethynylbenzaldehyde ,  2,4-Dihydroxy-3-methyl-6-(3-pentene-1-ynyl)benzaldehyde ,  (2R)-2α-Hydroxy-2-methyl-5-(3-pentene-1-ynyl)-6-(hydroxymethylene)-4-cyclohexene-1,3-dione ,  (7R)-3-(1-Propenyl)-7β-hydroxy-7-methyl-7,8-dihydro-6H-2-benzopyran-6,8-dione ,  (7R)-3-(1-Propenyl)-7β-[2-methyl-4-(benzyloxy)-6-methoxybenzoyloxy]-7-methyl-7,8-dihydro-6H-2-benzopyran-6,8-dione ,  (7R)-3-(3-Hydroxy-1-propenyl)-7β-[2-methyl-4-(benzyloxy)-6-methoxybenzoyloxy]-7-methyl-7,8-dihydro-6H-2-benzopyran-6,8-dione ,  (7R)-3-(3-Oxo-1-propenyl)-7β-[2-methyl-4-(benzyloxy)-6-methoxybenzoyloxy]-7-methyl-7,8-dihydro-6H-2-benzopyran-6,8-dione ,  (7R)-6,8-Dioxo-7β-[2-methyl-4-(benzyloxy)-6-methoxybenzoyloxy]-7-methyl-7,8-dihydro-6H-2-benzopyran-3-acrylic acid tert-butyl ester ,  1,3-Dimesitylimidazolidine

Terms in the title (2)： 天然物 ,  不斉合成