Art

J-GLOBAL ID：200902235614644590   Reference number：06A0006660

Chiral base-catalyzed aldol reaction of trimethoxysilyl enol ethers: effect of water as an additive on stereoselectivities

キラル塩基を触媒とするトリメトキシシリルエノールエーテルのアルドール反応 添加物としての水の立体選択性に及ぼす影響

Author (4)： ORITO Yuya (Fac. of Medical and Pharmaceutial Sciences, Kumamoto Univ., 5-1 Oe-honmachi, Kumamoto 862 0973, JPN) ,  HASHIMOTO Shunichi (Graduate School of Pharmaceutical Schiences, Hokkaido Univ., Kita 12 Nishi 6, Kita-ku, Sapporo 060 0812, JPN) ,  ISHIZUKA Tadao (Fac. of Medical and Pharmaceutial Sciences, Kumamoto Univ., 5-1 Oe-honmachi, Kumamoto 862 0973, JPN) ,  NAKAJIMA Makoto (Fac. of Medical and Pharmaceutial Sciences, Kumamoto Univ., 5-1 Oe-honmachi, Kumamoto 862 0973, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 62  Issue： 2-3  Page： 390-400  Publication year： Jan. 09, 2006 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： enol ether ,...
Semi thesaurus term： Aldol condensation ,...

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JST classification (2)： Monocyclic alicyclic compounds in general  (CF04010E) ,  Naphthalenes  (CF06020D)

Substance index (25)： Benzaldehyde ,  Butyl lithium ,  Cyclohexanecarbaldehyde ,  2-Cyclohexen-1-one ,  1-(Trimethoxysiloxy)cyclohexene ,  Trimethoxy(1-cycloheptenyloxy)silane ,  α-(Trimethoxysiloxy)styrene ,  1-(Trimethoxysiloxy)cyclopentene ,  3-(Trimethoxysiloxy)-1H-indene ,  1-(Triethoxysiloxy)cyclohexene ,  1,1'-Bi(2-naphthol) ,  1,1′-Bi(3-bromo-2-naphthol) ,  1,1′-Bi(3-methyl-2-naphthol) ,  1,1′-Bi(3-phenyl-2-naphthol) ,  1,1′-Bi[3-(trifluoromethyl)-2-naphthol] ,  1,1′-Bi[3-chloro-2-naphthol] ,  1,1′-Bi(3-iodo-2-naphthol) ,  (2R)-2-[(αR)-α-(Trimethoxysilylsilyloxy)benzyl]cyclohexanone ,  (2S)-2-[(αR)-α-(Trimethoxysilylsilyloxy)benzyl]cyclohexanone ,  (1R,2R)-1-Phenyl-1-hydroxy-2,4,4-trimethyl-3-pentanone ,  2β-[(S)-1-Hydroxy-3-phenylpropyl]cyclohexanone ,  (R)-2-((R)-α-Hydroxybenzyl)cyclohexanone ,  2β-[(R)-α-Hydroxybenzyl]indan-1-one ,  2β-[(S)-Hydroxycyclohexylmethyl]indan-1-one ,  (2S)-2-[(S)-Hydroxycyclohexylmethyl]-2,3-dihydro-1H-indene-1-one

Terms in the title (7)： キラル ,  塩基 ,  触媒 ,  アルドール反応 ,  添加物 ,  水 ,  立体選択性