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J-GLOBAL ID：200902239531053049   Reference number：09A0408048

STUDIES TOWARD INTRAMOLECULAR CYCLOADDITION OF O-QUINODIMETHANE WITH AN OXAZOLE MOIETY

o-キノジメタンのオキサゾール単位との分子内環状付加に向けた研究

Author (3)： MATSUYA Yuji (Univ. Toyama, Toyama, JPN) ,  QIN Hongbo (Univ. Toyama, Toyama, JPN) ,  NEMOTO Hideo (Univ. Toyama, Toyama, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 79  Page： 773-779  Publication year： Apr. 01, 2009 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *cycloaddition ,  *oxygen heterocyclic compound ,  *nitrogen heterocyclic compound ,  *quinoid compound ,  cycloalkene ,  polynuclear aromatic hydrocarbon ,  sigmatropy ,  reaction mechanism ,  reaction path ,  reaction intermediate ,  substituent effect ,  aliphatic aldehyde ,  polymer ,  *diene ,  thermochemical reaction ,  thermal decomposition ,  aromatic aldehyde ,  paraformaldehyde ,  Heterocyclic Compounds, 3-Ring ,  *Oxazoles
Semi thesaurus term： *Oxazoles ,  *o-キノジメタン誘導体

JST classification (3)： Oxazoles,isoxazoles  (CF07080Y) ,  Rearrangement reaction,isomerization  (CF02070E) ,  Alkenes  (CF03030T)

Substance index (15)： Benzaldehyde ,  Tosylmethyl isocyanide ,  3-Methoxy-7-(3-hydroxypropyl)bicyclo[4.2.0]octa-1(6),2,4-triene-7-carbonitrile ,  4-Methoxy-1,2-dihydrobenzocyclobutene-1-(1-propanol) ,  1-(3-Bromopropyl)-4-methoxy-1,2-dihydrobenzocyclobutene-1-carbonitrile ,  3-Methoxy-7-(3-bromopropyl)bicyclo[4.2.0]octa-1(6),2,4-triene ,  1-Tosyl-4-[3-methoxy-7-cyanobicyclo[4.2.0]octa-1(6),2,4-triene-7-yl]butyl isocyanide ,  1-Tosyl-4-[3-methoxybicyclo[4.2.0]octa-1(6),2,4-triene-7-yl]butyl isocyanide ,  1-[3-(5-Phenyl-4-oxazolyl)propyl]-4-methoxy-1,2-dihydrobenzocyclobutene-1-carbonitrile ,  1-[3-(4-Oxazolyl)propyl]-4-methoxy-1,2-dihydrobenzocyclobutene-1-carbonitrile ,  3-Methoxy-7-[3-(oxazole-4-yl)propyl]bicyclo[4.2.0]octa-1(6),2,4-triene ,  (Z)-2-(2-Methyl-4-methoxyphenyl)-5-(5-phenyloxazole-4-yl)-2-pentenenitrile ,  (Z)-2-(2-Methyl-4-methoxyphenyl)-5-(oxazole-4-yl)-2-pentenenitrile ,  (E)-1-(2-Methyl-4-methoxyphenyl)-4-(oxazole-4-yl)-1-butene ,  (3aR)-3aβ-(Formylamino)-4β-hydroxy-7-methoxy-2,3,3a,4,5,9b-hexahydro-1H-benzo[e]indene-9b-carbonitrile

Reference (7)：

• For a review; H. Nemoto and K. Fukumoto, Tetrahedron, 1998, 54, 5425, and references cited therein.
• Y. Matsuya, T. Itoh, and H. Nemoto, Eur. J. Org. Chem., 2003, 2221; Y. Matsuya, H. Qin, M. Nagaoka, and H. Nemoto, Heterocycles, 2004, 62, 207; Y. Matsuya, S. Masuda, T. Itoh, T. Murai, and H. Nemoto, J. Org. Chem., 2005, 70, 6898; Y. Matsuya, N. Ohsawa, and H. Nemoto, J. Am. Chem. Soc., 2006, 128, 412; Y. Matsuya, N. Ohsawa, and H. Nemoto, J. Am. Chem. Soc., 2006, 128, 13072.
• N. Toyooka, M. Nagaoka, H. Kakuda, and H. Nemoto, Synlett, 2001, 1123; N. Toyooka, M. Nagaoka, E. Sasaki, H. Qin, H. Kakuda, and H. Nemoto, Tetrahedron, 2002, 58, 6097.
• Y. Matsuya, K. Sasaki, M. Nagaoka, H. Kakuda, N. Toyooka, N. Imanishi, H. Ochiai, and H. Nemoto, J. Org. Chem., 2004, 69, 7989; Y. Matsuya, K. Sasaki, H. Ochiai, and H. Nemoto, Bioorg. Med. Chem., 2007, 15, 424; D.-Y. Yu, Y. Matsuya, Q.-L. Zhao, K. Ahmed, Z.-L. Wei, H. Nemoto, and T. Kondo, Apoptosis, 2007, 12, 1523; Y. Matsuya, Y. Imamura, T. Miyahara, H. Ochiai, and H. Nemoto, Eur. J. Org. Chem., 2008, 1426.
• A. M. van Leusen, B. E. Hoogenboom, and H. Siderius, Tetrahedron Lett., 1972, 13, 2369.

Terms in the title (4)： o-キノジメタン ,  オキサゾール ,  環状付加 ,  研究