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J-GLOBAL ID：200902240280057021   Reference number：04A0722328

Total Synthesis of (±)-Nominine, a Heptacyclic Hetisine-Type Aconite Alkaloid

七環ヘチシン型トリカブトアルカロイドの(±)-ノミニンの全合成

Author (2)： MURATAKE H (Res. Foundation Itsuu Lab., Tokyo, JPN) ,  NATSUME M (Res. Foundation Itsuu Lab., Tokyo, JPN)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 43  Issue： 35  Page： 4646-4649  Publication year： Sep. 06, 2004 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *Aconitum carmichaelii ,...
Semi thesaurus term： bridged compound

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JST classification (3)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Alkaloids  (CF10030D) ,  Other natural substances of biological origin  (CF10090R)

Substance index (11)： Hetisine ,  Nominine ,  Kobusine ,  Pseudokobusine ,  6-(2-Bromo-5-methoxyphenethyl)-1,4-dioxaspiro[4.5]decane-7-carbaldehyde ,  (3R,8aα)-4aβ,3β,4β-[(Z)-1-[2-(Methoxymethoxy)ethoxy]-3-pentene-1,2,5-triyl]-3-(2-acetoxyethyl)-8β-cyano-8-methyldecalin-1-one ,  (2aR)-2aβ-Methyl-7β-(2-hydroxyethyl)-5aα,7,6α-[(Z)-1-[2-(methoxymethoxy)ethoxy]-3-pentene-1,2,5-triyl]-1,2,2a,3,4,5,5a,6,7,8bβ-decahydrobenzo[cd]indole-1-carboxylic acid benzyl ester ,  (2aR,8aβ,8bβ)-2aβ-Methyl-7β-(2-propynyl)-5aα,7,6α-[(Z)-1-(2-hydroxyethoxy)-3-pentene-1,2,5-triyl]dodecahydrobenzo[cd]indole-1-carboxylic acid benzyl ester ,  (3aR,5aα,10aα,10cα)-3aα-Methyl-8-methylene-10bβ,6aβ,9β-[1-(2-hydroxyethoxy)-1,2,3-propanetriyl]hexadecahydrodibenzo[cd,f]indole-5-carboxylic acid benzyl ester ,  (3aR,5aα,10aα,10cα)-3aα-Methyl-7α-acetoxy-8-methylene-10bβ,6aβ,9β-(1-hydroxy-1,2,3-propanetriyl)hexadecahydrodibenzo[cd,f]indole-5-carboxylic acid benzyl ester ,  (3aR,5aα,10aα,10cα)-3aα-Methyl-7α-acetoxy-8-methylene-5,10bβ,6aβ,9β-(1,1,2,3-propanetetryl)hexadecahydrodibenzo[cd,f]indole

Terms in the title (4)： 環 ,  トリカブトアルカロイド ,  ノミニン ,  全合成