Art
J-GLOBAL ID：200902240459999623   Reference number：07A1099310

Total synthesis of capsanthin and capsorubin using Lewis acid-promoted regio- and stereoselective rearrangement of tetrasubsutituted epoxides

Lewis酸触媒による四置換エポキシドの位置および立体選択的転位を利用したカプサンチンおよびカプソルビンの全合成
Author (2)：
YAMANO Yumiko

About YAMANO Yumiko

(Kobe Pharmaceutical Univ., Kobe, JPN)

About Kobe Pharmaceutical Univ., Kobe, JPN

, 
ITO Masayoshi

About ITO Masayoshi

(Kobe Pharmaceutical Univ., Kobe, JPN)

About Kobe Pharmaceutical Univ., Kobe, JPN


Material：
Organic & Biomolecular Chemistry  (Org Biomol Chem)

About Organic & Biomolecular Chemistry


Volume： 5  Issue： 19  Page： 3207-3212  Publication year： Oct. 07, 2007 
JST Material Number： A0499C  ISSN： 1477-0520  CODEN： OBCRAK  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)
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Lewis acid catalyst

About Lewis acid catalyst

,...
Semi thesaurus term：
Thesaurus term/Semi thesaurus term
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*epoxide

About epoxide


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JST classification (1)：
JST classification
Category name(code) classified by JST.
Carotenoids,other terpenoids 
(CF10025Z)

About Carotenoids,other terpenoids

Substance index (4)：
Substance index
Chemical Substance indexed to the Article.
Capsanthin

About Capsanthin

, 
Capsorubin

About Capsorubin

, 
(2E,4E)-3-Methyl-5-[(1S)-2,2,6α-trimethyl-4α-(tert-butyldimethylsiloxy)-7-oxabicyclo[4.1.0]heptane-1α-yl]-2,4-pentadienal

About (2E,4E)-3-Methyl-5-[(1S)-2,2,6α-trimethyl-4α-(tert-butyldimethylsiloxy)-7-oxabicyclo[4.1.0]heptane-1α-yl]-2,4-pentadienal

, 
(2E,4E)-6-(1,5,5-Trimethyl-3β-hydroxycyclopentane-1α-yl)-6-oxo-3-methyl-2,4-hexadienal

About (2E,4E)-6-(1,5,5-Trimethyl-3β-hydroxycyclopentane-1α-yl)-6-oxo-3-methyl-2,4-hexadienal

Terms in the title (8)：
Terms in the title
Keywords automatically extracted from the title.
Lewis酸触媒

About Lewis酸触媒

, 
置換

About 置換

, 
エポキシド

About エポキシド

, 
立体

About 立体

, 
転位

About 転位

, 
カプサンチン

About カプサンチン

, 
カプソルビン

About カプソルビン

, 
全合成

About 全合成


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