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J-GLOBAL ID：200902242989303215   Reference number：06A0032707

Synthesis of alicyclic esters via an intramolecular conjugate addition reaction. New method for generating (Z)-vinylcopper species from 1,1-dibromoalkenes

分子内共役付加反応を経由する脂環式エステルの合成 1,1-ジブロモアルケン類から(Z)-ビニル銅化学種を発生させる新しい方法

Author (5)： TANINO Keiji (Div. of Chemistry, Graduate School of Sci., Hokkaido Univ., Sapporo 060-0810, JPN) ,  ARAKAWA Keisuke (Div. of Chemistry, Graduate School of Sci., Hokkaido Univ., Sapporo 060-0810, JPN) ,  SATOH Mikiya (Div. of Chemistry, Graduate School of Sci., Hokkaido Univ., Sapporo 060-0810, JPN) ,  IWATA Yasuhiro (Div. of Chemistry, Graduate School of Sci., Hokkaido Univ., Sapporo 060-0810, JPN) ,  MIYASHITA Masaaki (Div. of Chemistry, Graduate School of Sci., Hokkaido Univ., Sapporo 060-0810, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 47  Issue： 6  Page： 861-864  Publication year： Feb. 06, 2006 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *alicyclic compound ,...

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JST classification (1)： 7 or more-membered monocyclic alicyclic compounds  (CF04060H)

Substance index (28)： (R)-1,1-Dibromo-3-methyl-4-(triisopropylsiloxy)-1-butene ,  (Dimethylcuprio(III)) lithium ,  (2E,4R)-4-Methyl-5-(triisopropylsiloxy)-2-pentene ,  (2Z,4R)-2-Iodo-4-methyl-5-(triisopropylsiloxy)-2-pentene ,  4,4-Dimethoxybutyronitrile ,  4-(Benzyloxy)butanenitrile ,  3-Cyano-5-(benzyloxy)pentanal dimethyl acetal ,  4-Cyano-6-(benzyloxy)hexanal dimethyl acetal ,  1,1-Dibromo-4-cyano-6-(benzyloxy)-1-hexene ,  1,1-Dibromo-5-cyano-7-(benzyloxy)-1-heptene ,  2-Methyl-5-cyano-7-(benzyloxy)-2-heptene ,  1,1-Dibromo-3-[2-(benzyloxy)ethyl]-6-methyl-1,5-heptadiene ,  5-[2-(Benzyloxy)ethyl]-7,7-dibromo-2,6-heptadienoic acid ethyl ester ,  (-)-Citronellal ,  (4R)-1,1-Dibromo-4,8-dimethyl-1,7-nonadiene ,  2,2-Dimethyl-3-[(R)-3-methyl-6,6-dibromo-5-hexenyl]oxirane ,  (6R)-6-Methyl-9,9-dibromo-2,8-nonadienoic acid ethyl ester ,  2-Methyl-5-[2-(benzyloxy)ethyl]-2-cyclopentene-1-acetic acid ethyl ester ,  2-Methyl-4-[2-(benzyloxy)ethyl]-2-cyclopentene-1-acetic acid ethyl ester ,  2-Methyl-6-[2-(benzyloxy)ethyl]-2-cyclohexene-1-acetic acid ethyl ester ,  (5R)-2,5α-Dimethyl-2-cycloheptene-1-acetic acid ethyl ester ,  Dibutylcuprio(III) lithium ,  Bis(trimethylsilylmethyl)cuprio(III) lithium ,  2-Butyl-5-[2-(benzyloxy)ethyl]-2-cyclopentene-1-acetic acid ethyl ester ,  2,2-Dimethyl-3-[(R)-2-[2-(benzyloxy)ethyl]-4,4-dibromo-3-butenyl]oxirane ,  α,α,2-Trimethyl-4-[2-(benzyloxy)ethyl]-2-cyclopentene-1-methanol ,  2,2-Dimethyl-3-[3-[2-(benzyloxy)ethyl]-5,5-dibromo-4-pentenyl]oxirane ,  2,2-Dimethyl-3-[3-[2-(benzyloxy)ethyl]-4-hexenyl]oxirane

Terms in the title (5)： 共役付加 ,  脂環 ,  エステル ,  銅 ,  化学種