Art

J-GLOBAL ID：200902244160141148   Reference number：08A1274151

Synthesis of methyl 4,6-O-benzylidene-2,3-dideoxy-5-thio-β-dl-threo-hex-2-enopyranoside via hetero-Diels-Alder reaction and unusual stabilities of 1,5-anhydro-4,6-O-benzylidene 2,3-dideoxy-5-thio-dl-threo-hex-2-enitol

ヘテロ-Diels-Alder反応を経由するメチル4,6-O-ベンジリデン-2,3-ジデオキシ-5-チオ-β-DL-threo-2-ヘキセノピラノシドの合成及び1,5-アンヒドロ-4,6-O-ベンジリデン-2,3-ジデオキシ-5-チオ-DL-threo-2-ヘキセニトールの特異な安定性

Author (2)： WATANABE Yuhya (Graduate School of Integrated Sci., Yokohama City Univ., 22-2 Seto, Kanazawa-ku, Yokohama 236-0027, JPN) ,  SAKAKIBARA Tohru (Graduate School of Integrated Sci., Yokohama City Univ., 22-2 Seto, Kanazawa-ku, Yokohama 236-0027, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 65  Issue： 3  Page： 599-606  Publication year： Jan. 17, 2009 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *thiosugar ,  *anhydro sugar ,  glycoside ,  functional group protection ,  chemical synthesis ,  *Diels-Alder reaction ,  Pummerer reaction ,  optical resolution ,  stereoisomer ,  stability ,  ab initio method ,  proton magnetic resonance
Semi thesaurus term： conformation isomer

JST classification (2)： Thiopyrans  (CF07094Z) ,  Electronic structure of molecules  (BH05010Q)

Substance index (9)： Acetic acid-1,3-butadienyl ,  Mercaptoacetic acid ethyl ,  3-Acetoxy-3,6-dihydro-2H-thiopyran-2-carboxylic acid ethyl ester ,  (2R)-3α-Hydroxy-3,6-dihydro-2H-thiopyran-2α-methanol ,  (1α,6α)-3β-Phenyl-2,4-dioxa-7-thiabicyclo[4.4.0]deca-9-ene ,  (1α,6α)-3α-Phenyl-2,4-dioxa-7-thiabicyclo[4.4.0]deca-9-ene ,  (1α,6α)-3α-Phenyl-2,4-dioxa-7-thiabicyclo[4.4.0]deca-9-ene 7-oxide ,  (1α,6α)-3α-Phenyl-8β-methoxy-2,4-dioxa-7-thiabicyclo[4.4.0]deca-9-ene ,  (1α,6α)-3α-Phenyl-8α-methoxy-2,4-dioxa-7-thiabicyclo[4.4.0]deca-9-ene

Terms in the title (4)： ヘテロ-Diels-Alder反応 ,  ベンジリデン ,  DL ,  安定性