Art

J-GLOBAL ID：200902245498838647   Reference number：08A1110294

Simple Chiral Diene Ligands Provide High Enantioselectivities in Transition-Metal-Catalyzed Conjugate Addition Reactions

遷移金属接触共役付加反応において高エナンチオ選択性を提供する簡単なキラルジエン配位子

Author (3)： OKAMOTO Kazuhiro (Kyoto Univ., Kyoto, JPN) ,  HAYASHI Tamio (Kyoto Univ., Kyoto, JPN) ,  RAWAL Viresh H. (Univ. Chicago, Illinois)
Material： Organic Letters  (Org Lett)
Volume： 10  Issue： 19  Page： 4387-4389  Publication year： Oct. 02, 2008 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,  catalytic reaction ,  ligand effect ,  bridged compound ,  diene ,  cycloaddition ,  alcohol ,  enone ,  *rhodium catalyst ,  *addition reaction ,  *chiral ligand ,  monocyclic monoterpene
Semi thesaurus term： chiral ligand ,  *conjugate addition ,  tertiary alcohol

JST classification (2)： Bridged bicyclic carbocyclic compounds  (CF06100Q) ,  Catalytic reactions in general  (CB06080F)

Substance index (23)： (3R)-3-Phenylcyclohexanone ,  (R)-3-Phenylcycloheptanone ,  (4S)-4-Phenylnonane-2-one ,  2-Cyclohexen-1-one ,  2-Cyclohepten-1-one ,  3-Nonen-2-one ,  4-Methoxyphenylboronic acid ,  Phenylboronic acid ,  Methyl propiolate ,  α-Phellandrene ,  (1β,4β,7R)-α,α,5-Trimethyl-7-isopropylbicyclo[2.2.2]octa-2,5-diene-2-methanol ,  (1R,4R,7R)-5-Methyl-7-isopropylbicyclo[2.2.2]octa-2,5-diene-2-carboxylic acid methyl ester ,  (1R,4R,7R)-5-Methyl-7-isopropylbicyclo[2.2.2]octa-2,5-diene-2-methanol ,  (1R,4R,7R)-2-(Methoxymethyl)-5-methyl-7-isopropylbicyclo[2.2.2]octa-2,5-diene ,  (1R,4R,7R)-2-(1-Methoxy-1-methylethyl)-5-methyl-7-isopropylbicyclo[2.2.2]octa-2,5-diene ,  ((E)-Styryl)boronic acid ,  3α-(4-Methoxyphenyl)cyclohexanone ,  3α-[4-(Trifluoromethyl)phenyl]cyclohexanone ,  3α-(2-Methylphenyl)cyclohexanone ,  (R)-3-[(E)-Styryl]cyclohexanone ,  (R)-3-[(E)-1-Heptenyl]cyclohexanone ,  (R)-4-Phenyl-5-methyl-2-hexanone ,  (S)-4-Phenyl-4-(phenyldimethylsilyl)-2-butanone

Terms in the title (4)： 遷移金属 ,  共役付加 ,  エナンチオ選択性 ,  配位子