Art

J-GLOBAL ID：200902245829225195   Reference number：03A0205885

Stereospecific synthesis of eight- and nine-membered cyclic ethers by Eu(fod)₃-mediated cyclization of hydroxy epoxides.

ヒドロキシエポキシドのEu(fod)₃-仲介環化反応による八-および九員環状エーテルの立体特異的合成

Author (6)： SAITOH T (Niigata Univ., Niigata, JPN) ,  SUZUKI T (Niigata Univ., Niigata, JPN) ,  ONODERA N (Niigata Univ., Niigata, JPN) ,  SEKIGUCHI H (Niigata Univ., Niigata, JPN) ,  HAGIWARA H (Niigata Univ., Niigata, JPN) ,  HOSHI T (Niigata Univ., Niigata, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 44  Issue： 13  Page： 2709-2712  Publication year： Mar. 24, 2003 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,...

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JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (32)： rel-5-(3β^*-(Benzyloxymethyl)oxirane-2α^*-yl)-1-pentanol ,  rel-6-[3β^*-(Benzyloxymethyl)oxirane-2α^*-yl]-1-hexanol ,  rel-6-[3α^*-(Benzyloxymethyl)oxirane-2α^*-yl]-1-hexanol ,  rel-7-[3β^*-(Benzyloxymethyl)oxirane-2α^*-yl]-1-heptanol ,  rel-7-[3β^*-(Benzyloxymethyl)oxirane-2α^*-yl]-4-heptene-1-ol ,  rel-7-[3α^*-(Benzyloxymethyl)oxirane-2α^*-yl]-4-heptene-1-ol ,  (αS,2R)-α-(Benzyloxymethyl)oxepane-2β-methanol ,  (S)-1-[(2R)-Oxocane-2β-yl]-2-(benzyloxy)ethanol ,  (R)-1-[(2R)-Oxocane-2β-yl]-2-(benzyloxy)ethanol ,  (S)-1-[(2R)-Oxonane-2β-yl]-2-(benzyloxy)ethanol ,  (S)-1-[(2R)-2,3,4,7,8,9-Hexahydrooxonin-2β-yl]-2-(benzyloxy)ethanol ,  (R)-1-[(2R)-2,3,4,7,8,9-Hexahydrooxonin-2β-yl]-2-(benzyloxy)ethanol ,  (2R)-1-(Benzyloxy)-7-[(2S)-3β-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-5-heptene-2-ol ,  (2S)-1-(Benzyloxy)-7-[(2S)-3β-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-5-heptene-2-ol ,  (2R)-1-(Benzyloxy)-8-[(2S)-3β-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-6-octene-2-ol ,  (2S)-1-(Benzyloxy)-8-[(2S)-3β-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-6-octene-2-ol ,  (S)-1-[(2S)-8α-(Benzyloxymethyl)-3,6,7,8-tetrahydro-2H-oxocin-2α-yl]-2-(benzyloxy)ethanol ,  (S)-1-[(2S)-8β-(Benzyloxymethyl)-3,6,7,8-tetrahydro-2H-oxocin-2α-yl]-2-(benzyloxy)ethanol ,  (S)-1-[(2S)-9α-(Benzyloxymethyl)-2,3,6,7,8,9-hexahydrooxonin-2α-yl]-2-(benzyloxy)ethanol ,  (S)-1-[(2S)-9β-(Benzyloxymethyl)-2,3,6,7,8,9-hexahydrooxonin-2α-yl]-2-(benzyloxy)ethanol ,  (2R)-1-(Benzyloxy)-7-[(2S)-3α-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-5-heptene-2-ol ,  (2S)-1-(Benzyloxy)-7-[(2S)-3α-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-5-heptene-2-ol ,  (2R)-1-(Benzyloxy)-8-[(2S)-3α-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-6-octene-2-ol ,  (2S)-1-(Benzyloxy)-8-[(2S)-3α-(4-methoxybenzyloxymethyl)oxirane-2β-yl]-6-octene-2-ol ,  (R)-1-[(2S)-8α-(Benzyloxymethyl)-3,6,7,8-tetrahydro-2H-oxocin-2α-yl]-2-(benzyloxy)ethanol ,  (R)-1-[(2S)-8β-(Benzyloxymethyl)-3,6,7,8-tetrahydro-2H-oxocin-2α-yl]-2-(benzyloxy)ethanol ,  (R)-1-[(2S)-9α-(Benzyloxymethyl)-2,3,6,7,8,9-hexahydrooxonin-2α-yl]-2-(benzyloxy)ethanol ,  (R)-1-[(2S)-9β-(Benzyloxymethyl)-2,3,6,7,8,9-hexahydrooxonin-2α-yl]-2-(benzyloxy)ethanol ,  (2S)-2β-(4-Methoxybenzyloxymethyl)-8α-(benzyloxymethyl)-3,6,7,8-tetrahydro-2H-oxocin-3α-ol ,  (2S)-2β-(4-Methoxybenzyloxymethyl)-8β-(benzyloxymethyl)-3,6,7,8-tetrahydro-2H-oxocin-3α-ol ,  (2S)-2β-(4-Methoxybenzyloxymethyl)-9α-(benzyloxymethyl)-2,3,6,7,8,9-hexahydrooxonin-3α-ol ,  (2S)-2β-(4-Methoxybenzyloxymethyl)-9β-(benzyloxymethyl)-2,3,6,7,8,9-hexahydrooxonin-3α-ol

Terms in the title (5)： Eu ,  仲介 ,  環化反応 ,  環状エーテル ,  立体特異的合成