Art

J-GLOBAL ID：200902246023374650   Reference number：05A0597612

One-Step Synthesis of Triethynylvinylmethanes and Tetraethynylmethanes by GaCl₃-Promoted Diethynylation of 1,4-Enynes and 1,4-Diynes

GaCl₃によって促進された1,4-エニン類及び1,4-ジイン類のジエチニル化によるテトラエチニルメタン類及びトリエチニルビニルメタン類のワンステップ合成

Author (5)： AMEMIYA Ryo (Tohoku Univ., Sendai, JPN) ,  SUWA Katsunori (Tohoku Univ., Sendai, JPN) ,  TORIYAMA Junji (Tohoku Univ., Sendai, JPN) ,  NISHIMURA Yoshio (Tohoku Univ., Sendai, JPN) ,  YAMAGUCHI Masahiko (Tohoku Univ., Sendai, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 127  Issue： 23  Page： 8252-8253  Publication year： Jun. 15, 2005 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： one-pot synthesis ,...

   To see more with JDream III (charged).   {{ this.onShowAbsJLink("http://jdream3.com/lp/jglobal/index.html?docNo=05A0597612&from=J-GLOBAL&jstjournalNo=C0254A") }}

JST classification (2)： Organosilicon compounds  (CF08030C) ,  Group 13 organic compounds  (CF09030J)

Substance index (32)： Triethyl(4-pentene-1-ynyl)silane ,  (Chloroethynyl)triethylsilane ,  Tributyl(chloroethynyl)silane ,  3,3-Bis(triethylsilylethynyl)-5-(triethylsilyl)-1-pentene-4-yne ,  3,3-Bis(tributylsilylethynyl)-5-(triethylsilyl)-1-pentene-4-yne ,  Tributyl(4-pentene-1-ynyl)silane ,  tert-Butyldimethyl(4-pentene-1-ynyl)silane ,  3,3-Bis(triethylsilylethynyl)-5-(tributylsilyl)-1-pentene-4-yne ,  3,3-Bis(triethylsilylethynyl)-5-(tert-butyldimethylsilyl)-1-pentene-4-yne ,  3,3-Bis(triethylsilylethynyl)-5-(1-adamantyl)-1-pentene-4-yne ,  3,3-Bis(triethylsilylethynyl)-5-cyclohexyl-1-pentene-4-yne ,  3,3-Bis(triethylsilylethynyl)-1-nonene-4-yne ,  Triethyl(4-hexene-1-ynyl)silane ,  Triethyl(5-methyl-4-hexene-1-ynyl)silane ,  Triethyl(4-methyl-4-pentene-1-ynyl)silane ,  4,4-Bis(triethylsilylethynyl)-6-(triethylsilyl)-2-hexene-5-yne ,  2-Methyl-4,4-bis(triethylsilylethynyl)-6-(triethylsilyl)-2-hexene-5-yne ,  2-Methyl-3,3-bis(triethylsilylethynyl)-5-(triethylsilyl)-1-pentene-4-yne ,  Allyltrimethylsilane ,  2-Butenyltrimethylsilane ,  (6,6-Dimethyl-1,4-heptadiynyl)triethylsilane ,  Triethyl[5-(1-adamantyl)-1,4-pentadiynyl]silane ,  Triethyl(5-cyclohexyl-1,4-pentadiynyl)silane ,  2,2,8,8-Tetramethyl-3,6-nonadiyne ,  1-(1-Adamantyl)-6,6-dimethyl-1,4-heptadiyne ,  1,5-Bis(triethylsilyl)-1,4-pentadiyne ,  1-(Trimethylsilyl)-3,3-bis(triethylsilylethynyl)-6,6-dimethyl-1,4-heptadiyne ,  1-(Trimethylsilyl)-3,3-bis(triethylsilylethynyl)-5-(1-adamantyl)-1,4-pentadiyne ,  1-(Trimethylsilyl)-3,3-bis(triethylsilylethynyl)-5-cyclohexyl-1,4-pentadiyne ,  2,2,8,8-Tetramethyl-5,5-bis(triethylsilylethynyl)-3,6-nonadiyne ,  1-(1-Adamantyl)-3,3-bis(triethylsilylethynyl)-6,6-dimethyl-1,4-heptadiyne ,  1,5-Bis(trimethylsilyl)-3,3-bis(triethylsilylethynyl)-1,4-pentadiyne

Terms in the title (4)： GaCl3 ,  促進 ,  エニン ,  ジイン