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J-GLOBAL ID：200902247961051018   Reference number：08A0118193

AN ALTERNATIVE REGIOSELECTIVE RING-OPENING OF EPOXIDES TO CHLOROHYDRINS MEDIATED BY CHLOROTITANIUM(IV) REAGENTS

クロロチタン(IV)試薬が介在するエポキシドのクロロヒドリンへの別途位置選択的開環

Author (3)： NISHITANI Kiyoshi (Tokyo Univ. Sci. (Tokyo Rika Univ.), Chiba, JPN) ,  SHINYAMA Kyoko (Tokyo Univ. Sci. (Tokyo Rika Univ.), Chiba, JPN) ,  YAMAKAWA Koji (Tokyo Univ. Sci. (Tokyo Rika Univ.), Chiba, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 74  Page： 191-197  Publication year： Dec. 31, 2007 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ring-opening reaction ,...

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JST classification (2)： Three-membered heterocyclic compounds  (CF07050R) ,  Cyclization reaction,ring-opening reaction  (CF02050I)

Substance index (16)： 1-Chloro-2-dodecanol ,  1-Chloro-2-methyl-2-decanol ,  1-Phenyl-2-chloroethanol ,  2-Chloro-1-dodecanol ,  2-Chloro-2-phenylethanol ,  2-Chloro-2-methyl-1-decanol ,  2-Decyloxirane ,  Styrene oxide ,  2-Methyl-2-octyloxirane ,  2-Methyl-5-(1-chloro-1-methyl-2-hydroxyethyl)-2-cyclohexene-1-one ,  2-Methyl-5-(1-methyl-1-hydroxy-2-chloroethyl)-2-cyclohexene-1-one ,  5-(2-Methyloxiranyl)-2-methyl-2-cyclohexene-1-one ,  Dimethylformamide ,  Isopropanol ,  Methylene chloride ,  Titanium(IV)tetraisopropoxide

Reference (19)：

• K. Nishitani, Y. Harada, Y. Nakamura, K. Yokoo, and K. Yamakawa, Tetrahedron Lett., 1994, 35, 7809.
• P. A. Bartlett,“Asymmetric Synthesis”, Vol.3, ed. by J. D. Morrison, 1984, New York, Academic Press, pp. 411-454.
• For review; C. Bonini, and G. Righi, Synthesis, 1994, 225.
• C. Betti, D. Landini, and A. Maria, Synlett., 2006, 1335.
• B. C. Ranu and S. Benerjee, J. Org. Chem., 2005, 70, 4517.

Terms in the title (5)： 試薬 ,  エポキシド ,  クロロヒドリン ,  位置選択 ,  開環