Art

J-GLOBAL ID：200902248013949488   Reference number：03A0339142

Iron-Catalyzed Regio- and Stereoselective Ring Opening of [2.2.1]- and [3.2.1]Oxabicyclic Alkenes with a Grignard Reagent

鉄触媒を用いる[2.2.1]-および[3.2.1]オキサ二環式アルケン類のGrignard試薬による位置および立体選択的開環

Author (4)： NAKAMURA M (Univ. Tokyo, Tokyo, JPN) ,  MATSUO K (Univ. Tokyo, Tokyo, JPN) ,  INOUE T (Univ. Tokyo, Tokyo, JPN) ,  NAKAMURA E (Univ. Tokyo, Tokyo, JPN)
Material： Organic Letters  (Org Lett)
Volume： 5  Issue： 8  Page： 1373-1375  Publication year： Apr. 17, 2003 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *ring-opening reaction ,...
Semi thesaurus term： bridged compound

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JST classification (3)： Condensed derivatives of furan  (CF07073M) ,  Group 1 and group 2 organic compounds  (CF09020Y) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (24)： 4β,5β-Bis(methoxymethyl)-3β,6β-epoxycyclohexene ,  2α-Phenyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  4-Methoxyphenylmagnesium bromide ,  4-Methylphenylmagnesium bromide ,  2-Methylphenylmagnesium bromide ,  Vinylmagnesium bromide ,  Isobutenylmagnesium bromide ,  Ethylmagnesium bromide ,  Tetradecylmagnesium bromide ,  Isopropylmagnesium bromide ,  6β-(4-Methoxyphenyl)-2β,3β-bis(methoxymethyl)-4-cyclohexene-1β-ol ,  6β-(4-Methylphenyl)-2β,3β-bis(methoxymethyl)-4-cyclohexene-1β-ol ,  6β-(2-Methylphenyl)-2β,3β-bis(methoxymethyl)-4-cyclohexene-1β-ol ,  (1R)-2α-Vinyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  (1R)-2α-Isobutenyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  2α-Ethyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  (1R)-2α-Tetradecyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  (1R)-2α-Isopropyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  (4β)-1α-Methyl-5β,6β-bis(methoxymethyl)-7-oxabicyclo[2.2.1]hepta-2-ene ,  (1β,5β)-2,4-Dimethyl-8-oxabicyclo[3.2.1]octa-6-ene ,  1,4-Dihydro-1,4-epoxynaphthalene ,  2α-Phenyl-4-methyl-5α,6α-bis(methoxymethyl)-3-cyclohexene-1α-ol ,  (1R)-2α-Phenyl-5β,7β-dimethyl-6β-methoxy-3-cycloheptene-1α-ol ,  2α-Phenyl-1,2-dihydronaphthalene-1α-ol

Terms in the title (6)： 鉄触媒 ,  二環式 ,  アルケン ,  Grignard試薬 ,  立体 ,  開環