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J-GLOBAL ID：200902249326793051   Reference number：05A0629353

Effect of o-Methyl Group on Rate, Mechanism, and Resonance Contribution: Aminolysis of Y-Substituted Phenyl X-Substituted 2-Methylbenzoates

速度,機構および共鳴寄与へのo-メチル基の効果 Y-置換フェニルX-置換2-メチル安息香酸エステルの加アミン分解

Author (6)： UM Ik-Hwan (Ewha Womans Univ., Seoul, KOR) ,  LEE Ji-Youn (Ewha Womans Univ., Seoul, KOR) ,  LEE Hai Whang (Inha Univ., Inchon, KOR) ,  NAGANO Yoshiya (Kyushu Univ., Fukuoka, JPN) ,  FUJIO Mizue (Kyushu Univ., Fukuoka, JPN) ,  TSUNO Yuho (Kyushu Univ., Fukuoka, JPN)
Material： Journal of Organic Chemistry  (J Org Chem)
Volume： 70  Issue： 13  Page： 4980-4987  Publication year： Jun. 24, 2005 
JST Material Number： C0328A  ISSN： 0022-3263  CODEN： JOCEAH  Document type： Article
Article type： 原著論文  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *substituent effect ,...

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JST classification (3)： Aromatic monocyclic carboxylic esters,carboxylic anhydrides,acid halides  (CF05190E) ,  Solvolysis  (CF02040X) ,  Acid-base equilibrium  (CB04020D)

Substance index (13)： Piperidine ,  Piperidine-1-carbaldehyde ,  Morpholine ,  Piperazine-1-ethanol ,  2-Methyl-4-methoxybenzoic acid 4-nitrophenyl ester ,  2,4-Dimethylbenzoic acid 4-nitrophenyl ester ,  2-Methylbenzoic acid 4-nitrophenyl ester ,  2-Methyl-3-chlorobenzoic acid 4-nitrophenyl ester ,  2-Methyl-3-nitrobenzoic acid 4-nitrophenyl ester ,  2-Methylbenzoic acid 3-acetylphenyl ester ,  2-Methylbenzoic acid 4-acetylphenyl ester ,  2-Methylbenzoic acid 4-formylphenyl ester ,  2-Methylbenzoic acid 3,4-dinitrophenyl ester

Terms in the title (8)： 共鳴 ,  メチル基 ,  置換フェニル ,  置換 ,  2-メチル安息香酸 ,  エステル ,  アミン ,  分解