Art

J-GLOBAL ID：200902249646196230   Reference number：04A0108856

Cyclization of dienols, polyenes, and dienyne mediated by mercuric salts: course of cyclizations controlled by stability of cationic intermediates.

第二水銀塩が介するジエノール,ポリエン,及びジエニンの環化 カチオン性中間体の安定性によって制御される環化経路

Author (6)： TAKAO H (Tokushima Bunri Univ., Tokushima, JPN) ,  WAKABAYASHI A (Tokushima Bunri Univ., Tokushima, JPN) ,  TAKAHASHI K (Tokushima Bunri Univ., Tokushima, JPN) ,  IMAGAWA H (Tokushima Bunri Univ., Tokushima, JPN) ,  SUGIHARA T (Tokushima Bunri Univ., Tokushima, JPN) ,  NISHIZAWA M (Tokushima Bunri Univ., Tokushima, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 45  Issue： 5  Page： 1079-1082  Publication year： Jan. 26, 2004 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *diene ,...

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JST classification (1)： Alkynes  (CF03040E)

Substance index (23)： (E)-5,9-Dimethyl-4,8-decadien-1-ol ,  Acetic acid mercury ,  Mercury triflate ,  2-Methyl-3β-[chloromercurio(II)]-2α-(4-methyl-3-pentenyl)tetrahydro-2H-pyran ,  (4aα)-5,5,8aβ-Trimethyl-6β-[chloromercurio(II)]octahydro-2H-1-benzopyran ,  3-(1α-Chloromercurio(II)-2,2,4-trimethyl-3-cyclohexene-3-yl)propane-1-ol ,  (E)-9-Methyl-4,8-decadiene-1-ol ,  (Z)-9-Methyl-4,8-decadiene-1-ol ,  (E)-4,9-Dimethyl-4,8-decadiene-1-ol ,  (2S)-2-[(S)-1-[Chloromercurio(II)]-5-methyl-4-hexenyl]tetrahydrofuran ,  (2R)-2α-(4-Methyl-3-pentenyl)-3β-[acetoxymercurio(II)]tetrahydro-2H-pyran ,  (1R)-1β-[Chloromercurio(II)]-2α-(3-hydroxypropyl)-3-isopropylidenecyclopentane ,  (5aα,8aβ)-1,1-Dimethyl-6α-[chloromercurio(II)]octahydro-1H-cyclopenta[c]oxepin ,  (2R)-2α-(4-Methyl-3-pentenyl)-3α-[chloromercurio(II)]tetrahydro-2H-pyran ,  (2S)-2α-[(1R)-1-[Chloromercurio(II)]-5-methyl-4-hexenyl]-2-methyltetrahydrofuran ,  2,7,11-Trimethyl-1,6,10-dodecatriene ,  2,3,4,5,6,7-Hexahydro-1,4,4-trimethyl-5β-[chloromercurio(II)]-1α-isopropyl-1H-indene ,  2,11-Dimethyl-1,6,10-dodecatriene ,  (1R)-1β-[Chloromercurio(II)]-2α-(4-methyl-3-pentenyl)-3-isopropylidenecyclopentane ,  2,7,11,15-Tetramethyl-2,6,10,14-hexadecatetrene ,  (3R)-3β,6,6,9aβ-Tetramethyl-3-isopropyl-7β-[chloromercurio(II)]-2,3,4,5,5aα,6,7,8,9,9a-decahydro-1H-cyclopenta[a]naphthalene ,  3-Methyl-2-butenyl 7-methyl-6-octene-2-ynyl ether ,  1,1-Dimethyl-4-[chloromercurio(II)]-3,5,6,6a-tetrahydro-1H-cyclopenta[c]furan

Terms in the title (8)： 水銀 ,  塩 ,  ポリエン ,  環化 ,  カチオン ,  中間体 ,  安定性 ,  経路