Art

J-GLOBAL ID：200902250028559613   Reference number：04A0635772

Highly Regio- and Stereoselective Rearrangement of Epoxides to Aldehydes Catalyzed by High-Valent Metalloporphyrin Complex, Cr(TPP)OTf

高原子価-金属ポルフィリン錯体Cr(TPP)OTf触媒を用いたエポキシドのアルデヒドへの高度に位置-および立体選択的な転位

Author (4)： SUDA K (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  KIKKAWA T (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  NAKAJIMA S (Meiji Pharmaceutical Univ., Tokyo, JPN) ,  TAKANAMI T (Meiji Pharmaceutical Univ., Tokyo, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 126  Issue： 31  Page： 9554-9555  Publication year： Aug. 11, 2004 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *rearrangement reaction ,...
Semi thesaurus term： bridged compound

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JST classification (3)： Three-membered heterocyclic compounds  (CF07050R) ,  Rearrangement reaction,isomerization  (CF02070E) ,  6A and 7A groups  (CE01080F)

Substance index (23)： Tetraphenylporphyrin ,  2-(tert-Butyldimethylsiloxymethyl)-3-phenyloxirane ,  1-Phenyl-3-(tert-butyldimethylsiloxy)-2-propanone ,  2-Phenyl-3-(tert-butyldimethylsiloxy)propanal ,  2-(Triphenylsiloxymethyl)-3,3-dimethyloxirane ,  2,3-Epoxy-8-(tert-butyldimethylsiloxy)-2,6-dimethyloctane ,  2-Butyl-1-oxaspiro[2.5]octane ,  1-Phenylcyclohexene oxide ,  2α-(tert-Butyldimethylsiloxymethyl)-3β-phenyloxirane ,  2β-(tert-Butyldimethylsiloxymethyl)-3α-phenyloxirane ,  (2R)-2β-[(S)-1-(tert-Butyldimethylsiloxy)ethyl]-3α-phenyloxirane ,  (2S)-2α-Methyl-2-(4-methyl-3-pentenyl)-3α-(tert-butyldimethylsiloxymethyl)oxirane ,  (2S)-2α-Methyl-2-(4-methyl-3-pentenyl)-3β-(tert-butyldimethylsiloxymethyl)oxirane ,  (2S)-2β-(Triphenylsiloxymethyl)-2-phenyl-3α-isopropyloxirane ,  2,2-Dimethyl-3-(triphenylsiloxy)propanal ,  2,2,5-Trimethyl-7-(tert-butyldimethylsiloxy)heptanal ,  1-Butylcyclohexanecarbaldehyde ,  1-Phenylcyclopentanecarbaldehyde ,  (R)-2-Phenyl-3-(tert-butyldimethylsiloxy)propanal ,  (2S)-2-Phenyl-3-(tert-butyldimethylsiloxy)propanal ,  (2S,3S)-2-Phenyl-3-(tert-butyldimethylsiloxy)butanal ,  (S)-2-(tert-Butyldimethylsiloxymethyl)-2,6-dimethyl-5-heptenal ,  (2S)-2-Phenyl-2-(triphenylsiloxymethyl)-3-methylbutanal

Terms in the title (10)： 原子価 ,  ポルフィリン錯体 ,  Cr ,  TPP ,  OTF ,  触媒 ,  エポキシド ,  アルデヒド ,  立体 ,  転位