Art

J-GLOBAL ID：200902250161620279   Reference number：03A0710523

Enantioface-Selective Palladium-Catalyzed Silaboration of Allenes via Double Asymmetric Induction.

二重不斉誘導を経るパラジウム触媒によるアレン類のエナンチオ面選択的なシラほう素化

Author (6)： SUGINOME M (Kyoto Univ., Kyoto, JPN) ,  OHMURA T (Kyoto Univ., Kyoto, JPN) ,  MIYAKE Y (Kyoto Univ., Kyoto, JPN) ,  MITANI S (Kyoto Univ., Kyoto, JPN) ,  ITO Y (Kyoto Univ., Kyoto, JPN) ,  MURAKAMI M (Kyoto Univ., Kyoto, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 125  Issue： 37  Page： 11174-11175  Publication year： Sep. 17, 2003 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： asymmetric reaction ,...
Semi thesaurus term： シラほう素化

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JST classification (3)： Organoboron compounds  (CF08020R) ,  Organosilicon compounds  (CF08030C) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (31)： 5-Phenyl-1,2-pentadiene ,  (4R)-2-(Phenyldimethylsilyl)-4α,5β-dimethyl-1,3,2-dioxaborolane ,  4β,5α-Diphenyl-2-(dimethylphenylsilyl)-1,3,2-dioxaborolane ,  (4S)-2-(Phenyldimethylsilyl)-1,3,2-dioxaborolane-4α,5β-dicarboxylic acid diisopropyl ester ,  (4R)-2-(Phenyldimethylsilyl)-4α,6β-dimethyl-1,3,2-dioxaborinane ,  (7aβ)-2-[1-[1-(Phenyldimethylsilyl)-3-phenylpropyl]vinyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aS,7aβ)-2-[1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-3aα,8,8-trimethyl-4α,6α-methanohexahydro-1,3,2-benzodioxaborole ,  (4R)-2-[1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-4α,5β-dimethyl-1,3,2-dioxaborolane ,  (4S)-2-[1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-4β,5α-diphenyl-1,3,2-dioxaborolane ,  (4S)-2-[1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-1,3,2-dioxaborolane-4α,5β-dicarboxylic acid diisopropyl ester ,  (4R)-2-[1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-4α,6β-dimethyl-1,3,2-dioxaborinane ,  (3aR,7aβ)-2-[(2S)-1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aR,7aβ)-2-[(2R)-1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aS,7aβ)-2-[(2S)-1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-3aα,8,8-trimethyl-4α,6α-methanohexahydro-1,3,2-benzodioxaborole ,  (3aS,7aβ)-2-[(2R)-1-Methylene-2-(phenyldimethylsilyl)-4-phenylbutyl]-3aα,8,8-trimethyl-4α,6α-methanohexahydro-1,3,2-benzodioxaborole ,  1,2-Butadiene ,  5-(Phenyldimethylsiloxy)-1,2-pentadiene ,  1-Cyclohexylpropadiene ,  1-Phenylpropadiene ,  1-Propadienyl-4-methoxybenzene ,  [4-(Trifluoromethyl)phenyl]allene ,  (3aR,7aβ)-2-[(2S)-1-Methylene-2-(phenyldimethylsilyl)propyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aR,7aβ)-2-[(2S)-1-Methylene-2-(phenyldimethylsilyl)-4-(phenyldimethylsilyloxy)butyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aR,7aβ)-2-[(2S)-1-Methylene-2-(phenyldimethylsilyl)-2-cyclohexylethyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aR,7aβ)-2-[(2R)-1-Methylene-2-(phenyldimethylsilyl)-2-phenylethyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aR,7aβ)-2-[(2R)-1-Methylene-2-(phenyldimethylsilyl)-2-(4-methoxyphenyl)ethyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  (3aR,7aβ)-2-[(2R)-1-Methylene-2-(phenyldimethylsilyl)-2-[4-(trifluoromethyl)phenyl]ethyl]-3aβ,8,8-trimethyl-4β,6β-methanohexahydro-1,3,2-benzodioxaborole ,  1,1′-Binaphthalene-2,2′-diylbisoxy(diisopropylamino)phosphine ,  2-(Diphenylphosphino)-2′-methoxy-1,1′-binaphthalene ,  1,1′-Binaphthalene-2-yldiphenylphosphine ,  (2R)-2β-Cyclohexyloxepane-4-one

Terms in the title (4)： 不斉誘導 ,  パラジウム触媒 ,  アレン ,  ほう素化