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J-GLOBAL ID：200902254508630550   Reference number：03A0235042

Crossed Aldol Reaction Using Polymer-bound Lithium Amides.

重合体に結合したリチウムアミドを用いる交差アルドール反応

Author (4)： SEKI A (Yokohama National Univ., Yokohama) ,  TAKIZAWA Y (Yokohama National Univ., Yokohama) ,  ISHIWATA F (Yokohama National Univ., Yokohama) ,  ASAMI M (Yokohama National Univ., Yokohama)
Material： Chemistry Letters  (Chem Lett)
Volume： 32  Issue： 4  Page： 342-343  Publication year： Apr. 05, 2003 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： supported catalyst ,...
Semi thesaurus term： *Aldol condensation

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JST classification (4)： Aliphatic ketones  (CF03190Q) ,  Aliphatic aldehydes  (CF03180F) ,  Addition reaction,elimination reaction  (CF02030M) ,  Other catalysts  (CB06123Z)

Substance index (27)： 3-Pentanone ,  Benzaldehyde ,  Cyclohexanone ,  4-Chlorobenzaldehyde ,  2-Methoxybenzaldehyde ,  Cinnamaldehyde ,  3-Phenylpropanal ,  Butyraldehyde ,  Isobutyraldehyde ,  2-Pentanone ,  4-Methyl-3-penten-2-one ,  Cyclohexanecarbaldehyde ,  (1R,2R)-1-Phenyl-1-hydroxy-2-methyl-3-pentanone ,  (1R,2R)-1-(4-Chlorophenyl)-1-hydroxy-2-methyl-3-pentanone ,  (1R,2R)-1-(2-Methoxyphenyl)-1-hydroxy-2-methyl-3-pentanone ,  (4R,5S,6E)-4-Methyl-5-hydroxy-7-phenyl-6-heptene-3-one ,  (4R,5S)-4-Methyl-5-hydroxy-7-phenyl-3-heptanone ,  (4R,5S)-4-Methyl-5-hydroxy-3-octanone ,  2β-[(S)-α-Hydroxybenzyl]cyclohexanone ,  2β-[(R)-1-Hydroxy-3-phenylpropyl]cyclohexanone ,  2β-[(R)-1-Hydroxy-2-methylpropyl]cyclohexanone ,  1-Hydroxy-1-phenyl-3-hexanone ,  6-Hydroxy-8-phenyl-4-octanone ,  1-Cyclohexyl-1-hydroxy-3-hexanone ,  6-Hydroxy-7-methyl-4-octanone ,  1-Hydroxy-1-phenyl-5-methyl-4-hexene-3-one ,  1-Phenyl-3-oxo-1-butanol

Reference (19)：

• 1) C. H. Heathcock, in “Modern Synthetic Methods,” ed. by R. Scheffold, Verlag Helvetica Chimica Acta, Basel (1992), Vol. 6, p 1;
•  C. H. Heathcock, in “Comprehensive Organic Synthesis,” ed. by B. M. Trost and I. Fleming, Pergamon Press, Oxford (1991), Vol. 2, p 181.
• 2) For recent reviews; S. J. Shuttleworth, S. M. Allin, R. D. Wilson, and D. Nasturica, Synthesis, 2000, 1035;
•  S. V. Ley, I. R. Baxendale, R. N. Bream, P. S. Jackson, A. G. Leach, D. A. Longbottom, M. Nesi, J. S. Scott, R. I. Storer, and S. J. Taylor, J. Chem. Soc., Perkin Trans. 1, 2000, 3815;
•  Y. R. de Miguel, J. Chem. Soc., Perkin Trans. 1, 2000, 4213;

Terms in the title (4)： 重合体 ,  リチウムアミド ,  交差 ,  アルドール反応