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J-GLOBAL ID：200902259619652997   Reference number：03A0813816

Enantioselective 1,3-Dipolar Cycloaddition Reaction of Nitrones with α,β-Unsaturated Aldehydes Catalyzed by Cationic 3-Oxobutylideneaminatocobalt(III) Complexes

ニトロンとα,β-不飽和アルデヒドのカチオン性3-オキソブチリデンアミナートコバルト(III)錯体により触媒されるエナンチオ選択的1,3-双極環状付加反応

Author (7)： KEZUKA S (Keio Univ., Yokohama) ,  OHTSUKI N (Keio Univ., Yokohama) ,  MITA T (Keio Univ., Yokohama) ,  KOGAMI Y (Keio Univ., Yokohama) ,  ASHIZAWA T (Keio Univ., Yokohama) ,  IKENO T (Keio Univ., Yokohama) ,  YAMADA T (Keio Univ., Yokohama)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 76  Issue： 11  Page： 2197-2207  Publication year： Nov. 15, 2003 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *unsaturated aldehyde ,...

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JST classification (4)： Thiazoles,isothiazoles  (CF07081P) ,  Configuration and conformation of molecules  (BH05022J) ,  Cobalt bnd nickel complexes  (CE01092Y) ,  Crystal structure of heterocyclic compounds  (BK08030Q)

Substance index (18)： 1-Cyclopentene-1-carbaldehyde ,  Acrolein ,  Methacrolein ,  2-Butenal ,  3,3′-[[(1R,2R)-1,2-Cyclohexanediyl]bis(nitrilomethylidyne)]bis(4-mesityl-4-oxo-2-butene-2-olanion) ,  N-Benzylideneaniline N-oxide ,  (3R)-2,3α-Diphenyl-4α,5α-propanoisoxazolidine-4-methanol ,  N-(4-Methoxybenzylidene)aniline N-oxide ,  (3R)-2-Phenyl-3α-(4-methoxyphenyl)-4α,5α-propanoisoxazolidine-4-methanol ,  N-(4-Methylbenzylidene)aniline N-oxide ,  (3R)-2-Phenyl-3α-(4-methylphenyl)-4α,5α-propanoisoxazolidine-4-methanol ,  N-(4-Chlorobenzylidene)aniline N-oxide ,  (3R)-2-Phenyl-3α-(4-chlorophenyl)-4α,5α-propanoisoxazolidine-4-methanol ,  2-Butylacrylaldehyde ,  (3S)-2-Phenyl-3α-(2,3-dichlorophenyl)isoxazolidine-4β-methanol ,  (3S)-2-Phenyl-3α-(2,3-dichlorophenyl)-5α-methylisoxazolidine-4β-methanol ,  (3S)-2-Phenyl-3α-(2,3-dichlorophenyl)-5-methylisoxazolidine-5β-methanol ,  (3S)-2-Phenyl-3α-(2,3-dichlorophenyl)-5-butylisoxazolidine-5β-methanol

Reference (42)：

• 1) a) J. J. Tufariello, “1,3-Dipolar Cycloaddition Chemistry,” ed by A. Padwa, Wiley, New York (1984), Vol. 2, p. 83.
•  b) K. B. G. Trossell, “Nitrile Oxides, Nitrones and Nitronates in Organic Synthesis,” VCH, New York (1988).
•  c) “Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry toward Heterocycles and Natural Products,” ed by A. Padwa and P. W. Pearson, Wiley & Sons, New York (2002).
• 2) R. Huisgen, Angew. Chem., 75, 604 (1963).
• 3) M. Fredrickson, Tetrahedron, 53, 403 (1997).

Terms in the title (6)： ニトロン ,  不飽和アルデヒド ,  カチオン ,  錯体 ,  触媒 ,  双極環状付加反応