Art

J-GLOBAL ID：200902259794288084   Reference number：09A1105754

Solid-state Transformation of Achiral Crystals to a Chiral Crystal by Guest Release from Host-Guest Inclusion Crystals of Achiral Host Compound

アキラルホスト化合物のホスト-ゲスト包接結晶からのゲストの放出によるアキラル結晶のキラル結晶への固体状態転移

Author (5)： SAITO Hironori (Dep. of Chemistry, Graduate School of Material Sci., Josai Univ.) ,  SUZUKI Mitsuaki (Dep. of Chemistry, Graduate School of Material Sci., Josai Univ.) ,  MIYAMAE Hiroshi (Dep. of Chemistry, Graduate School of Material Sci., Josai Univ.) ,  HAYASHI Naoto (Graduate School of Sci. and Engineering, Univ. of Toyama) ,  KOBAYASHI Keiji (Dep. of Chemistry, Graduate School of Material Sci., Josai Univ.)
Material： Chemistry Letters  (Chem Lett)
Volume： 38  Issue： 11  Page： 1080-1081 (J-STAGE)  Publication year： 2009 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： guest host effect ,  *optical isomerism ,  *phase transition ,  *clathrate compound ,  heat treatment ,  recrystallization ,  steric conformation ,  molecular structure ,  X-Ray Diffraction ,  crystal structure ,  hydrogen bond ,  crystal lattice ,  space group ,  racemization ,  aliphatic chlorine compound ,  aliphatic carboxylic acid ,  carboxamide ,  oxygen heterocyclic compound ,  nitrogen heterocyclic compound ,  aliphatic nitrile ,  aliphatic ketone ,  *chirality ,  *host-guest complex
Semi thesaurus term： *host-guest inclusion complex

JST classification (2)： Molecular compounds  (CE02000C) ,  Thiophenes  (CF07074D)

Substance index (7)： Methylene chloride ,  Dimethylformamide ,  1,4-Dioxane ,  Pyridine ,  Acetonitrile ,  Acetone ,  (Thieno[3,2-b]thiophene-2,5-diyl)bis(diphenylmethanol)

Reference (19)：

• 1) a) J. Jacques, A. Collet, S. H. Wilen, Enantiomers, Racemates, and Resolutions, Krieger, Malbar, 1994.
•  b) G. R. Desiraju, Crystal Engineering, The Design of Organic Solids, Elsevier, Amsterdam, 1989.
• 2) P. A. Levkin, V. Y. Torbeev, D. A. Lenev, R. G. Kostyanovsky, <I>Topics in Stereochemistry</I>, John Wiley & Sons, Hoboken, <B>2006</B>, Vol. 25, pp. 81–134.
• 3) S. Piyarom, E. Yonemochi, T. Oguchi, K. Yamamoto, J. Pharm. Pharmacol. 1997, 49, 384;
•  F. Toda, K. Tanaka, H. Miyamoto, H. Koshima, I. Miyahara, K. Hirotsu, J. Chem. Soc., Perkin Trans. 2 1997, 1877.

Terms in the title (5)： 結晶 ,  放出 ,  アキラル ,  キラル結晶 ,  固体状態