Art

J-GLOBAL ID：200902261781379255   Reference number：04A0642414

Highly efficient chiral copper Schiff-base catalyst for asymmetric cyclopropanation of 2,5-dimethyl-2,4-hexadiene

2,5-ジメチル-2,4-ヘキサジエンの不斉シクロプロパン化用の非常に効率的なキラル銅Schiff塩基触媒

Author (6)： ITAGAKI M (Sumitomo Chemical Co. Ltd., Osaka, JPN) ,  HAGIYA K (Sumitomo Chemical Co. Ltd., Osaka, JPN) ,  KAMITAMARI M (Sumitomo Chemical Co. Ltd., Osaka, JPN) ,  MASUMOTO K (Sumitomo Chemical Co. Ltd., Osaka, JPN) ,  SUENOBU K (Sumitomo Chemical Co. Ltd., Osaka, JPN) ,  YAMAMOTO Y (Hiroshima Univ., Higashi-Hiroshima, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 60  Issue： 36  Page： 7835-7843  Publication year： Aug. 30, 2004 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： catalytic reaction ,...
Semi thesaurus term： Schiff base ,...

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JST classification (2)： Cyclopropanes  (CF04020P) ,  Complexes of 9 and 10 groups  (CE01050Y)

Substance index (13)： 2,5-Dimethyl-2,4-hexadiene ,  2-Diazoacetic acid tert-butyl ester ,  Diazoacetic acid ethyl ,  Triethoxyaluminum ,  Diacetic acid copper(II) salt ,  2-[[[1-Methyl-2,2-bis(2-methoxyphenyl)-2-hydroxyethyl]imino]methyl]phenol ,  2-[[[1-Methyl-2,2-bis(2-methoxyphenyl)-2-hydroxyethyl]imino]methyl]-4-nitrophenol ,  2-[[[1-Methyl-2,2-bis(2-butoxy-5-tert-butylphenyl)-2-hydroxyethyl]imino]methyl]phenol ,  2-[[1-Methyl-2,2-bis(2-butoxy-5-tert-butylphenyl)-2-hydroxyethyl]iminomethyl]-4-nitrophenol ,  (1R)-trans-Ethyl chrysanthemate ,  2,2-Dimethyl-3β-isobutenylcyclopropane-1β-carboxylic acid ethyl ester ,  2,2-Dimethyl-3α-(2-methyl-1-propenyl)cyclopropane-1β-carboxylic acid tert-butyl ester ,  2,2-Dimethyl-3β-(2-methyl-1-propenyl)cyclopropane-1β-carboxylic acid tert-butyl ester

Terms in the title (7)： ジメチル ,  ジエン ,  シクロプロパン化 ,  キラル ,  銅 ,  Schiff塩基 ,  触媒