Art

J-GLOBAL ID：200902261863168600   Reference number：09A0547818

Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine-Iridium System

シリカ担持コンパクトホスフィン-イリジウム系触媒を用いた官能基化アレーンの指向性オルトボリル化

Author (5)： KAWAMORITA Soichiro (Hokkaido Univ., Sapporo, JPN) ,  OHMIYA Hirohisa (Hokkaido Univ., Sapporo, JPN) ,  HARA Kenji (Hokkaido Univ., Sapporo, JPN) ,  FUKUOKA Atsushi (Hokkaido Univ., Sapporo, JPN) ,  SAWAMURA Masaya (Hokkaido Univ., Sapporo, JPN)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 131  Issue： 14  Page： 5058-5059  Publication year： Apr. 15, 2009 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： supported catalyst ,  phosphine complex ,  *iridium complex ,  iridium compound ,  transition metal catalyst ,  *boration ,  ester ,  *organic boron acid ,  regiospecific reaction ,  aromatic chlorine compound ,  aromatic carboxylic acid ,  carboxylate(ester) ,  silicon dioxide
Semi thesaurus term： silica ,  iridium catalyst ,  *borylation ,  *boronic acid ester ,  regioselective reaction

JST classification (3)： Nobel metal catalysts  (CB06122I) ,  Platinum family element complexes  (CE01100E) ,  Organoboron compounds  (CF08020R)

Substance index (18)： 2-(2-Chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborole ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)benzenesulfonic acid methyl ester ,  2-[2-(1,3-Dioxane-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  2-[2-[(Methoxymethoxy)methyl]phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ,  3,5-Dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  3,6-Dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  4-(Trifluoromethyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  4-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  5-(Trifluoromethyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  5-Isopropyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  5-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolane-2-yl)-6-(trifluoromethyl)benzoic acid methyl ester ,  6-Methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzoic acid methyl ester ,  N,N-Dimethyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)benzamide ,  N,N-Dimethylbenzamide ,  Chlorobenzene ,  Benzoic acid methyl

Terms in the title (7)： シリカ ,  担持 ,  イリジウム ,  触媒 ,  官能基化 ,  アレーン ,  指向性