Art

J-GLOBAL ID：200902263207726977   Reference number：03A0629324

Total Synthesis of the Antipode of Alkaloid 205 B.

アルカロイド205B対掌体の全合成

Author (4)： TOYOOKA N (Toyama Medical and Pharmaceutical Univ., Toyama, JPN) ,  FUKUTOME A (Toyama Medical and Pharmaceutical Univ., Toyama, JPN) ,  SHINODA H (Toyama Medical and Pharmaceutical Univ., Toyama, JPN) ,  NEMOTO H (Toyama Medical and Pharmaceutical Univ., Toyama, JPN)
Material： Angewandte Chemie. International Edition  (Angewandte Chemie. International Edition in English)
Volume： 42  Issue： 32  Page： 3808-3810  Publication year： Aug. 18, 2003 
JST Material Number： H0127B  ISSN： 1433-7851  CODEN： ACIEAY  Document type： Article
Article type： 短報  Country of issue： Germany, Federal Republic of (DEU)  Language： ENGLISH (EN)

Thesaurus term： *alkaloid ,...

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JST classification (1)： Alkaloids  (CF10030D)

Substance index (18)： (2aR)-3α,5α,7-Trimethyl-2,2aβ,3,4,5,5aβ,6,8aβ-octahydro-1H-pyrrolo[2,1,5-de]quinolizine ,  Alkaloid205B ,  (2aS)-3α,5β,7-Trimethyl-2,2aα,3,4,5,5aβ,6,8aβ-octahydro-1H-pyrrolo[2,1,5-de]quinolizine ,  6β-[(tert-Butyldiphenylsilyloxy)methyl]-5,6-dihydropyridine-1,2(4H)-dicarboxylic acid dimethyl ester ,  (3R)-3α-Methyl-6β-(tert-butyldiphenylsiloxymethyl)piperidine-1,2β-dicarboxylic acid dimethyl ester ,  (5S,8aβ)-5α-(tert-Butyldiphenylsiloxymethyl)-8β-methylhexahydrooxazolo[3,4-a]pyridine-3-one ,  (5S,8aβ)-3-Oxo-8β-methylhexahydrooxazolo[3,4-a]pyridine-5α-carboxylic acid methyl ester ,  (8R)-3-Oxo-8β-methyl-1,7,8,8aβ-tetrahydrooxazolo[3,4-a]pyridine-5-carboxylic acid methyl ester ,  (5R,8aβ)-3-Oxo-6α,8β-dimethylhexahydrooxazolo[3,4-a]pyridine-5β-carboxylic acid methyl ester ,  (5S,8aβ)-3-Oxo-6α,8β-dimethylhexahydrooxazolo[3,4-a]pyridine-5β-acetic acid methyl ester ,  (5S,8aβ)-5β-(2-Oxopropyl)-6α,8β-dimethylhexahydrooxazolo[3,4-a]pyridine-3-one ,  (2R)-2β-(Hydroxymethyl)-3α,5β-dimethyl-6α-(2-methyl-1,3-dioxolane-2-ylmethyl)-1-piperidinecarboxylic acid tert-butyl ester ,  (2R)-2β-[(E)-3-Oxo-3-ethoxy-1-propenyl]-3α,5β-dimethyl-6α-(2-methyl-1,3-dioxolane-2-ylmethyl)-1-piperidinecarboxylic acid tert-butyl ester ,  (2aS,2aα,5aα,8aβ)-6α,8β-Dimethyldecahydro-1H-pyrrolo[2,1,5-de]quinolizine-4-one ,  (2aS)-3α,5β-Dimethyl-2,2aα,3,4,5,5aβ,6,7,8,8aβ-decahydro-1H-pyrrolo[2,1,5-de]quinolizine-7-one ethylene acetal ,  Trifluoromethanesulfonic acid (2aS)-3α,5β-dimethyl-2,2aα,3,4,5,5aβ,6,8aβ-octahydro-1H-pyrrolo[2,1,5-de]quinolizine-7-yl ester ,  (2aS)-3α,5β-Dimethyl-7-methylene-2,2aα,3,4,5,5aβ,6,7,8,8aβ-decahydro-1H-pyrrolo[2,1,5-de]quinolizine ,  (2aS)-3α,5β,7-Trimethyl-2,2aα,3,4,5,5aβ,8,8aβ-octahydro-1H-pyrrolo[2,1,5-de]quinolizine

Terms in the title (3)： アルカロイド ,  対掌体 ,  全合成