Art

J-GLOBAL ID：200902263417012756   Reference number：06A0533722

Asymmetric 1,3-Dipolar Cycloaddition of Nitrones with an Electron-Withdrawing Group to Allylic Alcohols Utilizing Diisopropyl Tartrate as a Chiral Auxiliary

酒石酸ジイソプロピルをキラル助剤として用いる電子吸引性基をもつニトロンのアリルアルコールに対する不斉1,3-双極性環状付加

Author (7)： DING Xia (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  TANIGUCHI Katsumi (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  HAMAMOTO Yoshihira (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  SADA Kazunori (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  FUJINAMI Shuhei (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  UKAJI Yutaka (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.) ,  INOMATA Katsuhiko (Div. of Material Sciences, Graduate School of Natural Sci. and Technol., Kanazawa Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 79  Issue： 7  Page： 1069-1083 (J-STAGE)  Publication year： 2006 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *cycloaddition ,...
Semi thesaurus term： 亜鉛触媒 ,...

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JST classification (4)： Cyclization reaction,ring-opening reaction  (CF02050I) ,  Oxazoles,isoxazoles  (CF07080Y) ,  Complexes of 9 and 10 groups  (CE01050Y) ,  Configuration and conformation of molecules  (BH05022J)

Substance index (17)： Allyl alcohol ,  Diethyl zinc ,  Diisopropyl L-tartrate ,  N-(Cyanomethylene)benzeneamine N-oxide ,  N-(tert-Butoxycarbonylmethylene)methaneamine N-oxide ,  N-(Dibenzylcarbamoylmethylene)benzeneamine N-oxide ,  (3R)-2-Phenyl-5α-(hydroxymethyl)isoxazolidine-3β-carbonitrile ,  (3R)-2-Methyl-5α-(hydroxymethyl)isoxazolidine-3β-carboxylic acid tert-butyl ester ,  (3S)-N,N-Dibenzyl-2-phenyl-5α-(hydroxymethyl)isoxazolidine-3α-carboxamide ,  2-Buten-1-ol ,  2-Hexen-1-ol ,  Crotonic acid methyl ,  N-Benzyl-2-oxo-2-(diisopropylamino)ethanimine N-oxide ,  N-(Diisopropylcarbamoylmethylene)benzenamine N-oxide ,  (3S)-N,N-Diisopropyl-2-phenyl-4-methyl-5α-(hydroxymethyl)isoxazolidine-3α-carboxamide ,  (3S)-N,N-Diisopropyl-2-phenyl-4-propyl-5α-(hydroxymethyl)isoxazolidine-3α-carboxamide ,  (3S)-N,N-Diisopropyl-2-phenyl-4-(methoxycarbonyl)-5α-(hydroxymethyl)isoxazolidine-3α-carboxamide

Reference (68)：

• 1) a) Advances in Cycloaddition, ed. by D. P. Curran, Jai Press Inc., Greenwich, 1988, Vol. 1;
•  Advances in Cycloaddition, ed. by D. P. Curran, Jai Press Inc., Greenwich, 1990, Vol. 2.
•  b) W. Carruthers, Cycloaddition Reactions in Organic Synthesis, Pergamon Press, Oxford, 1990.
• 2) a) K. Mikami, T. Nakai, Kagaku, Zokan 1995, 124, 177.
•  b) D. A. Evans, J. S. Johnson, Comprehensive Asymmetric Catalysis, ed. by E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer, Berlin, 1999, Chap. 33.1.

Terms in the title (8)： 酒石酸 ,  ジイソプロピル ,  キラル ,  助剤 ,  電子吸引性基 ,  ニトロン ,  アリルアルコール ,  環状付加