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J-GLOBAL ID：200902266596759620   Reference number：05A0863028

The Yukawa-Tsuno Relationship for the β-Silicon Effect in the Solvolysis Rates of 2-(Aryldimethylsilyl)ethyl Chlorides

2-(アリールジメチルシリル)エチルクロリドの加溶媒分解速度におけるβ-けい素効果に関するYukawa-Tsuno相関

Author (7)： FUJIO Mizue (Inst. for Materials Chemistry and Engineering, Kyushu Univ.) ,  UCHIDA Mai (Inst. for Materials Chemistry and Engineering, Kyushu Univ.) ,  OKADA Ayumi (Inst. for Materials Chemistry and Engineering, Kyushu Univ.) ,  ALAM Md. Ashadul (Inst. for Materials Chemistry and Engineering, Kyushu Univ.) ,  FUJIYAMA Ryoji (Dep. of Material Sci., Fac. of Sci., Kochi Univ.) ,  SIEHL Hans-ullrich (Div. of Organic Chemistry 1, Univ. of Ulm) ,  TSUNO Yuho (Inst. for Materials Chemistry and Engineering, Kyushu Univ.)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 78  Issue： 10  Page： 1834-1842 (J-STAGE)  Publication year： 2005 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *solvolysis ,...
Semi thesaurus term： Yukawa-Tsuno式

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JST classification (3)： Organosilicon compounds  (CF08030C) ,  Solvolysis  (CF02040X) ,  Noncatalytic liquid phase reactions  (CB06060J)

Substance index (1)： 2-Chloroethylphenyldimethylsilane

Reference (46)：

• 1) a) J. B. Lambert, G. T. Wang, R. B. Finzel, and D. H. Teramura, J. Am. Chem. Soc., 109, 7838 (1987).
•  b) J. B. Lambert and E. C. Chelius, J. Am. Chem. Soc., 112, 8120 (1990);
•  J. B. Lambert, R. W. Emblidge, and S. Malany, J. Am. Chem. Soc., 115, 1317 (1993).
• 2) Y. Apeloig, “The Chemistry of Organic Silicon Compounds,” ed by S. Patai and Z. Rappoport, John Wiley & Sons, Chichester (1989), Chap. 2, p. 57, and references cited therin.
• 3) a) J. B. Lambert, Tetrahedron, 46, 2677 (1990);

Terms in the title (4)： エチルクロリド ,  加溶媒分解 ,  けい素 ,  相関