Art

J-GLOBAL ID：200902266615376150   Reference number：07A0803733

Intramolecular rearrangement of 1,3-bistriflate ester of thiacalix[4]arene to 1,2-counterpart: an efficient di-O-protection method for the stereoselective synthesis of anti-1,2-diethers

チアカリックス[4]アレーンの1,3-ビストリフラートエステルの1,2-対応物への分子内転位: anti-1,2-ジエーテル類を立体選択的に合成するための効率的なジ-O-保護法

Author (5)： SERIZAWA Ryuichi (Dep. of Environmental Studies, Graduate School of Environmental Studies, Tohoku Univ., 6-6-11 Aramaki-Aoba, Aoba-ku ...) ,  TANAKA Shinya (Dep. of Environmental Studies, Graduate School of Environmental Studies, Tohoku Univ., 6-6-11 Aramaki-Aoba, Aoba-ku ...) ,  MOROHASHI Naoya (Dep. of Environmental Studies, Graduate School of Environmental Studies, Tohoku Univ., 6-6-11 Aramaki-Aoba, Aoba-ku ...) ,  NARUMI Fumitaka (Dep. of Basic Sciences, School of Sci. and Engineering, Ishinomaki Senshu Univ., 1 Shinmito, Minamisakai, Ishinomaki ...) ,  HATTORI Tetsutaro (Dep. of Environmental Studies, Graduate School of Environmental Studies, Tohoku Univ., 6-6-11 Aramaki-Aoba, Aoba-ku ...)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 48  Issue： 36  Page： 6281-6285  Publication year： Sep. 03, 2007 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： stereospecific reaction ,...
Semi thesaurus term： *calixarene ,...

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JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Rearrangement reaction,isomerization  (CF02070E)

Substance index (8)： 4-t-Butylthiacalix[4]arene ,  6,6′-[2-(Trifluoromethylsulfonyloxy)-5-tert-butyl-1,3-phenylenebisthio][2,2′-[2-(trifluoromethylsulfonyloxy)-5-tert-butyl-1,3-phenylenebisthio]bis(4-tert-butylphenol)] ,  6,6′-[Thiobis[[2-(trifluoromethylsulfonyloxy)-5-tert-butyl-1,3-phenylene]thio]][2,2′-thiobis(4-tert-butylphenol)] ,  3,3′-[Thiobis[[2-(trifluoromethylsulfonyloxy)-5-tert-butyl-1,3-phenylene]thio]][1,1′-thiobis(2-methoxy-5-tert-butylbenzene)] ,  6,6′-[Thiobis[(2-methoxy-5-tert-butyl-1,3-phenylene)thio]][2,2′-thiobis(4-tert-butylphenol)] ,  6,6′-[Thiobis[[2-(benzyloxy)-5-tert-butyl-1,3-phenylene]thio]][2,2′-thiobis(4-tert-butylphenol)] ,  6,6′-[Thiobis[(2-butoxy-5-tert-butyl-1,3-phenylene)thio]][2,2′-thiobis(4-tert-butylphenol)] ,  6,6′-[Thiobis[[2-(2-oxo-2-ethoxyethoxy)-5-tert-butyl-1,3-phenylene]thio]][2,2′-thiobis(4-tert-butylphenol)]

Terms in the title (2)： アレーン ,  立体