Art

J-GLOBAL ID：200902266844157314   Reference number：05A0252584

Rhodium-Catalyzed Acylation of Vinylsilanes with Acid Anhydrides

ビニルシランの酸無水物によるロジウム触媒アシル化

Author (3)： YAMANE M (Univ. Tokyo, Tokyo) ,  UERA K (Univ. Tokyo, Tokyo) ,  NARASAKA K (Univ. Tokyo, Tokyo)
Material： Bulletin of the Chemical Society of Japan  (Bull Chem Soc Jpn)
Volume： 78  Issue： 3  Page： 477-486  Publication year： Mar. 15, 2005 
JST Material Number： G0450A  ISSN： 0009-2673  CODEN： BCSJA8  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *organosilicon compound ,...

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JST classification (3)： Organosilicon compounds  (CF08030C) ,  Platinum family element complexes  (CE01100E) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (16)： Acetic acid anhydride ,  Benzoic acid anhydride ,  (E)-1-(Phenyldimethylsilyl)-4-phenyl-1-butene ,  (E)-6-Phenyl-3-hexene-2-one ,  1-(Phenyldimethylsilyl)cyclopentene ,  1-Benzoylcyclopentene ,  Methyl ((E)-styryl) ketone ,  Dimethylphenyl[(Z)-styryl]silane ,  Benzoic acid (E)-1-(trimethylsilyl)-4-phenyl-1-butenyl ester ,  Benzoic acid (Z)-1-acetyl-4-phenyl-1-butenyl ester ,  Benzoic acid (E)-α-(trimethylsilyl)styryl ester ,  Benzoic acid (Z)-α-acetylstyryl ester ,  6-Phenyl-2,3-hexanedione ,  2,2-Dimethoxy-6-phenyl-3-hexanone ,  1-Phenyl-2,3-butanedione ,  1-Phenyl-3,3-dimethoxy-2-butanone

Reference (84)：

• 1) AlCl₃; a) I. Fleming and A. Pearce, J. Chem. Soc., Chem. Commun., 1975, 633.
•  b) W. E. Fristad, D. S. Dime, T. R. Bailey, and L. A. Paquette, Tetrahedron Lett., 20, 1999 (1979).
•  TiCl₄; c) A. Tubul and M. Santelli, Tetrahedron, 44, 3975 (1988).
•  SnCl₄; d) F. Cooke, R. Moerck, J. Schwindeman, and P. Magnus, J. Org. Chem., 45, 1046 (1980).
•  ZnCl₂; e) T. Sasaki, A. Nakanishi, and M. Ohno, J. Org. Chem., 47, 3219 (1982).

Terms in the title (4)： ビニルシラン ,  酸無水物 ,  ロジウム触媒 ,  アシル化