Art

J-GLOBAL ID：200902268481685502   Reference number：07A1191872

Asymmetric cyclization-carbonylation of 2-alkyl-2-propargylcyclohexane-1,3-diones: facile access to optically active hydrindanes

2-アルキル-2-プロパルギルシクロヘキサン-1,3-ジオンの不斉環化-カルボニル化 光学活性ヒドリンダン類への簡易法

Author (9)： KUSAKABE Taichi (Fac. of Pharmaceutical Sciences, Toho Univ., 2-2-1 Miyama, Funabashi, Chiba 274-8510, JPN) ,  KATO Keisuke (Fac. of Pharmaceutical Sciences, Toho Univ., 2-2-1 Miyama, Funabashi, Chiba 274-8510, JPN) ,  TAKAISHI Satoshi (Fac. of Pharmaceutical Sciences, Toho Univ., 2-2-1 Miyama, Funabashi, Chiba 274-8510, JPN) ,  YAMAMURA Shigeo (Fac. of Pharmaceutical Sciences, Josai International Univ., Gumyo 1, Togane, Chiba 283-8555, JPN) ,  MOCHIDA Tomoyuki (Dep. of Chemistry, Fac. of Sci., Kobe Univ., Rokkodai, Nada, Kobe 657-8501, JPN) ,  AKITA Hiroyuki (Fac. of Pharmaceutical Sciences, Toho Univ., 2-2-1 Miyama, Funabashi, Chiba 274-8510, JPN) ,  PEGANOVA Tat'yana A. (A.N. Nesmeyanov Inst. of Organoelement Compounds, The Russian Acad. of Sciences, Vavilov Street 28, 119991 Moscow, RUS) ,  VOLOGDIN Nikolai V. (A.N. Nesmeyanov Inst. of Organoelement Compounds, The Russian Acad. of Sciences, Vavilov Street 28, 119991 Moscow, RUS) ,  GUSEV Oleg V. (A.N. Nesmeyanov Inst. of Organoelement Compounds, The Russian Acad. of Sciences, Vavilov Street 28, 119991 Moscow, RUS)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 64  Issue： 2  Page： 319-327  Publication year： Jan. 07, 2008 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *alicyclic ketone ,...
Semi thesaurus term： bridged compound ,...

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JST classification (4)： Cyclohexanes  (CF04050W) ,  Cyclization reaction,ring-opening reaction  (CF02050I) ,  Oxidation,reduction  (CF02060T) ,  Alkynes  (CF03040E)

Substance index (18)： p-Benzoquinone ,  2-Methyl-2-propargyl-1,3-cyclohexanedione ,  [(2E,3aS,7aR)-3a-Methyl-4-oxo-7a-methoxyoctahydrobenzofuran-2-ylidene]acetic acid methyl ester ,  [(2E,3aS,7aR)-3a-Methyl-4-oxo-7a-isopropoxyoctahydrobenzofuran-2-ylidene]acetic acid isopropyl ester ,  [(2E,3aS,7aR)-3a-Methyl-4-oxo-7a-butoxyoctahydrobenzofuran-2-ylidene]acetic acid butyl ester ,  [(2E,3aS,7aR)-3a-Methyl-4-oxo-7a-(isobutyloxy)octahydrobenzofuran-2-ylidene]acetic acid isobutyl ester ,  2,2′-Isopropylidenebis[(4R)-4-(1-naphthyl)-2-oxazoline] ,  2,2′-Isopropylidenebis[(4R)-4-(2-naphthyl)-2-oxazoline] ,  2,2′-Isopropylidenebis[(4R)-4-(4-tert-butylphenyl)-2-oxazoline] ,  2,2′-Isopropylidenebis[(4R)-4-(4-methoxyphenyl)-2-oxazoline] ,  2,2′-Isopropylidenebis[(4R)-4-(3,4-dimethoxyphenyl)-2-oxazoline] ,  2,2-Bis[3aβ,8aβ-dihydro-8H-indeno[1,2-d]oxazole-2-yl]propane ,  [(2E,3aR,7aS)-3a-Methyl-4-oxo-7a-(isobutyloxy)octahydrobenzofuran-2-ylidene]acetic acid isobutyl ester ,  (3aR)-2-Oxo-3a-methyl-4-methylene-3,3a,4,5,6,7-hexahydro-2H-indene-1-carboxylic acid isobutyl ester ,  (3aR)-2-Oxo-3a-propyl-4-methylene-3,3a,4,5,6,7-hexahydro-2H-indene-1-carboxylic acid isobutyl ester ,  (3aS)-2-Oxo-3a-methyl-4-methylene-3,3a,4,5,6,7-hexahydro-2H-indene-1-carboxylic acid methyl ester ,  (3aR)-2-Oxo-3a-propyl-4-methylene-3,3a,4,5,6,7-hexahydro-2H-indene-1-carboxylic acid methyl ester ,  [(2E,3aS,7aβ)-3aα-Methyl-4α-hydroxyoctahydrobenzofuran-2-ylidene]acetic acid methyl ester

Terms in the title (7)： プロパルギルシクロヘキサン ,  ジオン ,  環化 ,  カルボニル化 ,  光学活性 ,  ヒドリンダン ,  簡易法