Art

J-GLOBAL ID：200902269819337684   Reference number：09A1217973

Platinum(II)-catalyzed Acetal-Ene Reaction: Easy Access to Homoallylic Ethers

白金(II)を触媒に用いるアセタール-エン反応 ホモアリルエーテルへの容易なアクセス

Author (5)： MIURA Katsukiyo (Dep. of Applied Chemistry, Graduate School of Sci. and Engineering, Saitama Univ.) ,  IZUMI Hiroyuki (Dep. of Chemistry, Graduate School of Pure and Applied Sciences, Univ. of Tsukuba) ,  KINOSHITA Hidenori (Dep. of Applied Chemistry, Graduate School of Sci. and Engineering, Saitama Univ.) ,  ICHIKAWA Junji (Dep. of Chemistry, Graduate School of Pure and Applied Sciences, Univ. of Tsukuba) ,  HOSOMI Akira (Dep. of Chemistry, Graduate School of Pure and Applied Sciences, Univ. of Tsukuba)
Material： Chemistry Letters  (Chem Lett)
Volume： 38  Issue： 12  Page： 1204-1205 (J-STAGE)  Publication year： 2009 
JST Material Number： S0742A  ISSN： 0366-7022  CODEN： CMLTAG  Document type： Article
Article type： 短報  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *platinum catalyst ,  *silver catalyst ,  platinum chloride ,  fluoro acid ,  antimony compound ,  silver compound ,  *acetalation ,  *ene reaction ,  consecutive reaction ,  reaction mechanism ,  chemical synthesis ,  cleavage reaction ,  *allyl compound ,  *ether ,  C-C bond ,  tandem reaction
Semi thesaurus term： アリルエーテル類 ,  fluoroantimonate silver

JST classification (2)： Addition reaction,elimination reaction  (CF02030M) ,  Catalytic reactions(homogeneous system)  (CB06090Q)

Substance index (20)： 1-(2-Methoxydecyl)-1-cyclohexene ,  1-(2-Methoxy-2-cyclohexylethyl)-1-cyclohexene ,  1-(β-Methoxyphenethyl)-1-cyclohexene ,  1-(2-Methoxy-4-phenylbutyl)-1-cyclohexene ,  1-[2-Methoxy-2-(4-chlorophenyl)ethyl]-1-cyclohexene ,  1-[2-Methoxy-2-(4-methylphenyl)ethyl]-1-cyclohexene ,  1-Methyl-1-cyclohexene ,  2,4-Diphenyl-2,4-dimethoxybutane ,  2,4-Diphenyl-4-methoxy-1-butene ,  2-Phenyl-2-methoxypropane ,  2-Methyl-1-heptene ,  Benzenepropanal dimethyl acetal ,  α,α-Dimethoxy(p-chlorotoluene) ,  4-Dimethoxymethyltoluene ,  α-Methylstyrene ,  (Dimethoxymethyl)cyclohexane ,  Trifluoromethanesulfonic acid silver(I) ,  1,1-Dimethoxynonane ,  Methylenecyclohexane ,  Benzaldehyde dimethyl acetal

Reference (16)：

• 1) a) B. B. Snider, in Comprehensive Organic Synthesis, ed. by B. M. Trost, I. Fleming, Pergamon, Oxford, 1991, Vol. 2, pp. 527–561.
•  b) D. J. Berrisford, C. Bolm, Angew. Chem., Int. Ed. Engl. 1995, 34, 1717.
•  c) K. Mikami, M. Terada, in Comprehensive Asymmetric Catalysis, ed. by E. N. Jacobsen, A. Pfaltz, H. Yamamoto, Springer Verlag, Berlin, 1999, Vol. III, pp. 1143–1174.
• 2) a) B. B. Snider, Acc. Chem. Res. 1980, 13, 426.
•  b) K. Mikami, M. Shimizu, Chem. Rev. 1992, 92, 1021.

Terms in the title (6)： 白金 ,  触媒 ,  アセタール ,  エン反応 ,  ホモ ,  アリルエーテル