Art

J-GLOBAL ID：200902271679769540   Reference number：08A0278402

One-pot synthesis of macrocyclic compounds possessing two cyclobutane rings by sequential inter- and intramolecular [2+2] photocycloaddition reactions

逐次的な分子間-及び分子内[2+2]光環状付加反応による2個のシクロブタン環を持つ大環状化合物のワンポット合成

Author (7)： MIYAUCHI Hideki (Dep. of Applied Chemistry and Chemical Engineering, Fac. of Engineering, Kagoshima Univ., Korimoto, Kagoshima ...) ,  IKEMATSU Chie (Dep. of Applied Chemistry and Chemical Engineering, Fac. of Engineering, Kagoshima Univ., Korimoto, Kagoshima ...) ,  SHIMAZAKI Toshiaki (Inst. for Materials Chemistry and Engineering (IMCE), Kyushu Univ., Hakozaki, Fukuoka 812-8581, JPN) ,  KATO Shinichiro (Inst. for Materials Chemistry and Engineering (IMCE), Kyushu Univ., Hakozaki, Fukuoka 812-8581, JPN) ,  SHINMYOZU Teruo (Inst. for Materials Chemistry and Engineering (IMCE), Kyushu Univ., Hakozaki, Fukuoka 812-8581, JPN) ,  SHIMO Tetsuro (Dep. of Applied Chemistry and Chemical Engineering, Fac. of Engineering, Kagoshima Univ., Korimoto, Kagoshima ...) ,  SOMEKAWA Kenichi (Dep. of Applied Chemistry and Chemical Engineering, Fac. of Engineering, Kagoshima Univ., Korimoto, Kagoshima ...)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 64  Issue： 18  Page： 4108-4116  Publication year： Apr. 28, 2008 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *macrocyclic compound ,  *lactone ,  asymmetric synthesis ,  one-pot synthesis ,  regiospecific reaction ,  *photocycloaddition ,  photocyclization ,  sensitization (photography) ,  consecutive reaction ,  reaction mechanism ,  radical reaction ,  molecular orbital method ,  frontier orbital ,  crystal structure ,  aliphatic alcohol ,  aliphatic carboxylic acid ,  olefin compound ,  unsaturated carboxylic acid ,  carboxylate (ester) ,  diol

JST classification (2)： Eight or more-membered heterocyclic compounds  (CF07120T) ,  Electronic structure of molecules  (BH05010Q)

Substance index (12)： 4,4′-(m-Xylylenebisoxy)bis(6-methyl-2H-pyran-2-one) ,  Ethylene glycol diacrylate ,  Ethylene glycol dimethacrylate ,  Diethylene glycol dimethacrylate ,  Triethylene glycol dimethylacrylate ,  5,5′-[1,3-Phenylenebis(methyleneoxy)]bis[(1S,6β)-1β-methyl-3-oxo-2-oxabicyclo[4.2.0]octa-4-ene-7β-carboxylic acid]ethylene ester ,  5,5′-[1,3-Phenylenebis(methyleneoxy)]bis[(1S,6β)-1β-methyl-3-oxo-7-methyl-2-oxabicyclo[4.2.0]octa-4-ene-7β-carboxylic acid]ethylene ester ,  5,5′-[1,3-Phenylenebis(methyleneoxy)]bis[(1S,6β)-1β-methyl-3-oxo-7-methyl-2-oxabicyclo[4.2.0]octa-4-ene-7β-carboxylic acid](oxybisethylene) ester ,  5,5′-[1,3-Phenylenebis(methyleneoxy)]bis[(1S,6β)-1β-methyl-3-oxo-7-methyl-2-oxabicyclo[4.2.0]octa-4-ene-7β-carboxylic acid]3,6-dioxaoctane-1,8-diyl ester ,  (1S,6β)-1β,7-Dimethyl-3-oxo-5,7β-[oxymethylene(1,3-phenylene)methyleneoxy[(1α)-2-oxo-4,7-dimethyl-3-oxabicyclo[4.2.0]octa-4-ene-6α,7β-diyl]carbonyloxyethyleneoxycarbonyl]-2-oxabicyclo[4.2.0]octa-4-ene ,  7,7′-[Oxybis(ethyleneoxy)][6,6′-[1,3-phenylenebis(methyleneoxy)]bis(4-methyl-3-oxabicyclo[4.2.0]octa-4-ene-2-one)] ,  7,7′-[Ethylenebis(oxyethyleneoxy)][6,6′-[1,3-phenylenebis(methyleneoxy)]bis(4-methyl-3-oxabicyclo[4.2.0]octa-4-ene-2-one)]

Terms in the title (6)： 逐次 ,  光環状付加 ,  シクロブタン ,  環 ,  大環状化合物 ,  ワンポット合成