Art

J-GLOBAL ID：200902271933452927   Reference number：08A0307016

Synthesis of 1,2-dihydroisoquinolines via palladium(0)-catalyzed addition-cyclization of chloroform to ortho-alkynylaldimines

パラジウム(0)触媒を用いたクロロホルムのortho-アルキニルアルジミンへの付加-環化による1,2-ジヒドロイソキノリン類の合成

Author (3)： NAKAMURA Hiroyuki (Dep. of Chemistry, Fac. of Sci., Gakushuin Univ., Mejiro, Tokyo 171-8588, JPN) ,  SAITO Hiroyuki (Dep. of Chemistry, Fac. of Sci., Gakushuin Univ., Mejiro, Tokyo 171-8588, JPN) ,  NANJO Masato (Dep. of Chemistry, Fac. of Sci., Gakushuin Univ., Mejiro, Tokyo 171-8588, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 49  Issue： 17  Page： 2697-2700  Publication year： Apr. 21, 2008 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： chemical synthesis ,  *nitrogen heterocyclic compound ,  *polynuclear aromatic compound ,  catalytic reaction ,  palladium catalyst ,  acetylenic compound ,  azomethine ,  addition reaction ,  cyclization reaction ,  reaction mechanism ,  aliphatic chlorine compound ,  trihalomethane ,  *Isoquinolines
Semi thesaurus term： *Isoquinolines

JST classification (1)： Quinolines,isoquinolines  (CF07096H)

Substance index (25)： Chloroform ,  N-[2-(1-Hexynyl)benzylidene]aniline ,  1-(Trichloromethyl)-2-phenyl-3-butyl-1,2-dihydroisoquinoline ,  N-(2-Methoxyphenyl)-2-(1-hexynyl)benzenemethaneimine ,  N-(4-Methoxyphenyl)-2-(1-hexynyl)benzenemethaneimine ,  N-(3-Chlorophenyl)-2-(1-hexynyl)benzenemethaneimine ,  N-Propyl-2-(1-hexynyl)benzenemethaneimine ,  N-(3-Pyridinyl)-2-(1-hexynyl)benzenemethaneimine ,  N-[2-(Phenylethynyl)benzylidene]aniline ,  N-(2-Methoxyphenyl)-2-(phenylethynyl)benzenemethaneimine ,  N-(3-Methoxyphenyl)-2-(phenylethynyl)benzenemethaneimine ,  4-Methoxy-N-[2-(phenylethynyl)benzylidene]aniline ,  N-(2-Methoxybenzyl)-2-[3-(dicyclohexylamino)-1-propynyl]benzenemethaneimine ,  N-Benzyl-2-[3-(dicyclohexylamino)-1-propynyl]benzenemethaneimine ,  1-(Trichloromethyl)-2-(2-methoxyphenyl)-3-butyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-(4-methoxyphenyl)-3-butyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-(3-chlorophenyl)-3-butyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-propyl-3-butyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-(3-pyridinyl)-3-butyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2,3-diphenyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-(2-methoxyphenyl)-3-phenyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-(3-methoxyphenyl)-3-phenyl-1,2-dihydroisoquinoline ,  1-(Trichloromethyl)-2-(4-methoxyphenyl)-3-phenyl-1,2-dihydroisoquinoline ,  N,N-Dicyclohexyl-1-(trichloromethyl)-2-(2-methoxybenzyl)-1,2-dihydroisoquinoline-3-methaneamine ,  N,N-Dicyclohexyl-1-(trichloromethyl)-2-benzyl-1,2-dihydroisoquinoline-3-methaneamine

Terms in the title (4)： パラジウム ,  触媒 ,  クロロホルム ,  環化