Art

J-GLOBAL ID：200902272233604544   Reference number：07A0839612

Development of radical addition-cyclization-elimination reaction of oxime ether and its application to formal synthesis of (±)-martinelline

オキシムエーテルのラジカル付加-環化-脱離反応の開発及びそれの(±)-マルチネリンの形式合成への応用

Author (9)： MIYATA Okiko (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  SHIRAI Atsushi (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  YOSHINO Shintaro (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  NAKABAYASHI Toshiki (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  TAKEDA Yoshifumi (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  KIGUCHI Toshiko (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  FUKUMOTO Daisuke (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  UEDA Masafumi (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN) ,  NAITO Takeaki (Kobe Pharmaceutical Univ., 4-19-1, Motoyamakita, Higashinada, Kobe 658-8558, JPN)
Material： Tetrahedron  (Tetrahedron Symposia-in-Print)
Volume： 63  Issue： 40  Page： 10092-10117  Publication year： Oct. 01, 2007 
JST Material Number： E0234A  ISSN： 0040-4020  Document type： Article
Article type： 原著論文  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： radical reaction ,...
Semi thesaurus term： domino reaction ,...

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JST classification (3)： Aliphatic hydroxylamines,hydrazines and other polynitrogen compounds  (CF03080W) ,  Quinolines,isoquinolines  (CF07096H) ,  Labeled compounds  (CB10050N)

Substance index (23)： AIBN ,  Tributyltin ,  Martinelline ,  1-(Benzyloxycarbonyl)-4-(3-hydroxypropyl)-2,3,3aα,4,5,9bα-hexahydro-1H-pyrrolo[3,2-c]quinoline-8-carboxylic acid methyl ester ,  2-[[(E)-4-Oxo-4-ethoxy-2-butenyl]tosylamino]benzaldehyde O-benzyloxime ,  (E)-N-Benzyl-4-[N-tosyl-2-(benzyloxyiminomethyl)anilino]-2-buteneamide ,  (E)-4-[N-Tosyl-2-(benzyloxyiminomethyl)anilino]-2-butenenitrile ,  (E)-4-[N-Tosyl-2-(methoxyiminomethyl)anilino]-2-butenoic acid ethyl ester ,  1,8-Diacetoxy-5-(2-bromobenzoyl)-2,3,3aα,4,5,9bα-hexahydro-1H-pyrrolo[3,2-c]quinoline ,  1-(2-Bromobenzoyl)-1,2,3,4-tetrahydroquinoline ,  1-(2-Iodobenzoyl)-1,2,3,4-tetrahydroquinoline ,  4,5-Propanophenanthridine-6(5H)-one ,  5-Tosyl-1,3,3aα,4,5,9bα-hexahydro-2H-pyrrolo[3,2-c]quinoline-2-one ,  5-Tosyl-1,3,3aα,4,5,9bβ-hexahydro-2H-pyrrolo[3,2-c]quinoline-2-one ,  1-Tosyl-4β-(benzyloxyamino)-1,2,3,4-tetrahydroquinoline-3α-acetic acid ethyl ester ,  1-Tosyl-4β-amino-1,2,3,4-tetrahydroquinoline-3α-acetic acid tert-butyl ester ,  1-Tosyl-4β-(benzyloxyamino)-1,2,3,4-tetrahydroquinoline-3α-acetonitrile ,  5-Tosyl-2,3,3aα,4,5,9bα-hexahydrofuro[3,2-c]quinoline-2-one ,  9bα-Methyl-2,3,3aα,4,5,9b-hexahydrofuro[3,2-c]quinoline-2-one ,  5-Tosyl-(3-²H)2,3,3aα,4,5,9bα-hexahydrofuro[3,2-c]quinoline-2-one ,  9bβ-Methyl-(3-²H)2,3,3aα,4,5,9b-hexahydrofuro[3,2-c]quinoline-2-one ,  Dimethylaminotributylstannane ,  Tributyl(2H)stannane

Terms in the title (8)： オキシムエーテル ,  ラジカル付加 ,  環化 ,  脱離反応 ,  開発 ,  マルチネリン ,  形式合成 ,  応用