Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes

NISHIMURA Takahiro; TSURUMAKI Eiji; KAWAMOTO Takahiro; GUO Xun-Xiang; HAYASHI Tamio

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J-GLOBAL ID：200902272585790275 Reference number：08A1110212

Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes

アザベンゾノルボルナジエン類のロジウム触媒不斉開環アルキニル化

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Author (5)：

NISHIMURA Takahiro

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(Kyoto Univ., Kyoto, JPN)

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TSURUMAKI Eiji

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(Kyoto Univ., Kyoto, JPN)

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KAWAMOTO Takahiro

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(Kyoto Univ., Kyoto, JPN)

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GUO Xun-Xiang

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(Kyoto Univ., Kyoto, JPN)

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HAYASHI Tamio

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(Kyoto Univ., Kyoto, JPN)

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Material：

Organic Letters (Org Lett)

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Volume： 10 Issue： 18 Page： 4057-4060 Publication year： Sep. 18, 2008
JST Material Number： W1171A ISSN： 1523-7060 CODEN： ORLEF7 Document type： Article
Article type：短報 Country of issue： United States (USA) Language： ENGLISH (EN)

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bridged compound

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*nitrogen heterocyclic compound

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acetylenic compound

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*rhodium catalyst

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rhodium complex

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catalytic reaction

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asymmetric synthesis

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ring-opening reaction

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*alkynylation

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polynuclear aromatic compound

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phosphine complex

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chiral ligand

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*Naphthalenes

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Pyrroles

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JST classification (4)：

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Platinum family element complexes

(CE01100E)

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, Naphthalenes

(CF06020D)

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, Catalytic reactions in general

(CB06080F)

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, Condensed derivatives of pyrroles

(CF07077C)

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Substance index (10)：

Substance index
Chemical Substance indexed to the Article.

(1S)-9-(tert-Butoxycarbonyl)-1β,4β-epimino-1,4-dihydronaphthalene

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Ethynyltriisopropylsilane

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4,4′-Bi(5-(di(3,5-ditert-butyl-4-methoxyphenyl)phosphino)-1,3-benzodioxole)

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(2α-Ethynyl-3β-bromo-4α-methoxy-1,2,3,4-tetrahydronaphthalene-1α-yl)carbamic acid tert-butyl ester

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[2α-[(Triisopropylsilyl)ethynyl]-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester

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[2α-[(Triisopropylsilyl)ethynyl]-6,7-dimethyl-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester

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[2α-[(Triisopropylsilyl)ethynyl]-6,7-dimethoxy-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester

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[2α-[(Triisopropylsilyl)ethynyl]-6,7-difluoro-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester

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[2α-[(Triisopropylsilyl)ethynyl]-6,7-dibromo-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester

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[2α-[(Triisopropylsilyl)ethynyl]-6,7-dibromo-5,8-dimethyl-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester

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Search "J2.653.880G"
Search "[2α-[(Triisopropylsilyl)ethynyl]-6,7-dibromo-5,8-dimethyl-1,2-dihydronaphthalene-1α-yl]carbamic acid tert-butyl ester"
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Terms in the title (4)：

Terms in the title
Keywords automatically extracted from the title.

ベンゾノルボルナジエン

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ロジウム触媒

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開環

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アルキニル化

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