Art

J-GLOBAL ID：200902273459028127   Reference number：03A0772567

Asymmetric radical carbon-carbon bond forming reactions in chiral amides and imides under sulfonyl groups stereocontrol.

キラルなアミド及びイミドにおけるスルホニル基立体制御下での不斉ラジカル炭素-炭素結合の形成

Author (4)： HIROI K (Tohoku Pharmaceutical Univ., Miyagi, JPN) ,  KANEKO M (Tohoku Pharmaceutical Univ., Miyagi, JPN) ,  ISHII M (Tohoku Pharmaceutical Univ., Miyagi, JPN) ,  KATO F (Tohoku Pharmaceutical Univ., Miyagi, JPN)
Material： Tetrahedron: Asymmetry  (Tetrahedron Asym)
Volume： 14  Issue： 19  Page： 2875-2878  Publication year： Oct. 03, 2003 
JST Material Number： T0907A  ISSN： 0957-4166  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： asymmetric synthesis ,...

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JST classification (2)： Pyrroles  (CF07076L) ,  Structure effect on organic reaction  (CF02110Z)

Substance index (16)： Allyltributylstannane ,  Methylbis(2,6-ditert-butyl-4-methylphenoxy) aluminum ,  1-(2-Bromopropanoyl)-L-proline methyl ester ,  (1R)-2-[(R)-2-Methyl-4-pentenoyl]cyclopentanecarboxylic acid methyl ester ,  (2S)-5-Oxo-1-(2-bromopropionyl)pyrrolidine-2-carboxylic acid methyl ester ,  (1R)-3-Oxo-2-[(S)-2-methyl-4-pentenoyl]cyclopentanecarboxylic acid methyl ester ,  (2S)-1-(2-Methyl-2-bromo-3-oxobutyryl)pyrrolidine-2-carboxylic acid methyl ester ,  (2S)-1-[(R)-2-Methyl-2-allyl-3-oxobutyryl]pyrrolidine-2-carboxylic acid methyl ester ,  (2S)-5-Oxo-1-(2-methyl-2-bromo-3-oxobutyryl)pyrrolidine-2-carboxylic acid methyl ester ,  (2S)-5-Oxo-1-(2-methyl-2-bromo-3-oxobutyryl)pyrrolidine-2-carboxylic acid tert-butyl ester ,  (2S)-1-[(S)-2-Methyl-2-allyl-3-oxobutyryl]pyrrolidine-2-carboxylic acid methyl ester ,  (2S)-1-[(S)-2-Methyl-2-allyl-3-oxobutyryl]pyrrolidine-2-carboxylic acid tert-butyl ester ,  (2S)-5-Oxo-1-(2-tosyl-2-bromopropionyl)pyrrolidine-2-carboxylic acid methyl ester ,  (2S)-5-Oxo-1-(2-tosyl-2-bromopropionyl)pyrrolidine-2-carboxylic acid tert-butyl ester ,  (2S)-5-Oxo-1-[(R)-2-tosyl-2-methyl-4-pentenoyl]pyrrolidine-2-carboxylic acid methyl ester ,  (2S)-5-Oxo-1-[(R)-2-tosyl-2-methyl-4-pentenoyl]pyrrolidine-2-carboxylic acid tert-butyl ester

Terms in the title (7)： キラル ,  アミド ,  イミド ,  スルホニル基 ,  立体制御 ,  ラジカル ,  炭素-炭素結合