Art

J-GLOBAL ID：200902274694349948   Reference number：08A0561459

Zn-mediated rhodium-catalyzed α-trifluoromethylation of ketones via silyl enol ethers

ロジウム触媒を用いたシリルエノールエーテルを経るケトンの亜鉛媒介α-トリフルオロメチル化

Author (6)： SATO Kazuyuki (Fac. of Pharmaceutical Sciences, Setsunan Univ. 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, JPN) ,  YUKI Takashi (Fac. of Pharmaceutical Sciences, Setsunan Univ. 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, JPN) ,  TARUI Atsushi (Fac. of Pharmaceutical Sciences, Setsunan Univ. 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, JPN) ,  OMOTE Masaaki (Fac. of Pharmaceutical Sciences, Setsunan Univ. 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, JPN) ,  KUMADAKI Itsumaro (Fac. of Pharmaceutical Sciences, Setsunan Univ. 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, JPN) ,  ANDO Akira (Fac. of Pharmaceutical Sciences, Setsunan Univ. 45-1, Nagaotoge-cho, Hirakata, Osaka 573-0101, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 49  Issue： 22  Page： 3558-3561  Publication year： May. 26, 2008 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： catalytic reaction ,  rhodium catalyst ,  *ketone ,  *Methylation ,  enol ether ,  organosilicon compound ,  rhodium complex ,  substitution reaction ,  reaction mechanism ,  silyl enol ether ,  *trifluoromethylation ,  fron

JST classification (2)： Aliphatic ketones  (CF03190Q) ,  Substitution reaction  (CF02020B)

Substance index (11)： Diethyl zinc ,  Trifluoroiodomethane ,  2-(Trifluoromethyl)cyclohexanone ,  1-(Trimethylsilyloxy)-6-methylcyclohexene ,  1-(Trimethylsiloxy)cyclohexene ,  2-(Trimethylsiloxy)-3,3-dimethyl-4-phenyl-1-butene ,  5-(Trimethylsiloxy)-4-nonene ,  α-(Trimethylsiloxy)styrene ,  [3-(Trimethylsilyloxy)allyl]benzene ,  3-Phenyl-1-(trimethylsiloxy)-2-methyl-1-propene ,  1,1,1,6,6,6-Hexafluoro-3,4-bis(trimethylsiloxy)-3,4-diphenylhexane

Terms in the title (5)： ロジウム触媒 ,  シリルエノールエーテル ,  ケトン ,  亜鉛 ,  トリフルオロメチル化