Art

J-GLOBAL ID：200902275949760945   Reference number：09A1243420

SYNTHESIS OF OPTICALLY ACTIVE P-CHIROGENIC FERROCENE-FUSED BENZOPHOSPHOLE BY DIASTEREOSELECTIVE INTRAMOLECULAR CYCLIZATION OF PHOSPHANYLFERROCENE DERIVATIVES

ホスファニルフェロセン誘導体のジアステレオ選択的分子内環化による光学活性なP-キロゲン性フェロセン縮環ベンゾホスホールの合成

Author (7)： YASUIKE Shuji (Hokuriku Univ., Kanazawa, JPN) ,  HAGIWARA Jun-ichi (Hokuriku Univ., Kanazawa, JPN) ,  DANJO Hiroshi (Tokushima Bunri Univ., Sanuki, JPN) ,  KAWAHATA Masatoshi (Tokushima Bunri Univ., Sanuki, JPN) ,  KAKUSAWA Naoki (Hokuriku Univ., Kanazawa, JPN) ,  YAMAGUCHI Kentaro (Tokushima Bunri Univ., Sanuki, JPN) ,  KURITA Jyoji (Hokuriku Univ., Kanazawa, JPN)
Material： Heterocycles  (International Journal for Reviews and Communications in Heterocyclic Chemistry)
Volume： 78  Issue： 12  Page： 3001-3010  Publication year： Dec. 01, 2009 
JST Material Number： S0966A  ISSN： 0385-5414  CODEN： HTCYAM  Document type： Article
Article type： 原著論文  Country of issue： Japan (JPN)  Language： ENGLISH (EN)

Thesaurus term： *ferrocenes ,  *phosphorus heterocyclic compound ,  asymmetric synthesis ,  diastereomer ,  cyclization reaction ,  optical activity ,  synthetic intermediate ,  absolute configuration ,  X-ray diffraction ,  palladium complex ,  derivatization
Semi thesaurus term： X-ray crystallography

JST classification (1)： Organic Fe compound  (CF09056D)

Substance index (3)： [2-(2-Lithiophenyl)-2,4-cyclopentadienyl]diphenylphosphine ,  4-Methylphenyl[2-(2-bromophenyl)-2,4-cyclopentadienyl] sulfoxide ,  8-Phenyl-8-phospha-1H,8H-cyclopenta[a]indene

Reference (17)：

• I. Ojima, Ed.,‘Catalytic Asymmetric Synthesis, Second Edition,’ Wiley-VCH, New York, 2000.
• For selected recent reviews, see; P.-H. Leung, Acc. Chem. Res., 2004, 37, 169; K.-V. L. Crépy and T. Imamoto, Adv. Synth. Catal., 2003, 345, 79; K.-V. L. Crépy and T. Imamoto,‘Topics in current Chemistry: New Aspects in Phosphorous Chemistry III, New P-Chirogenic Phosphine ligands and Their Use in Catalytic Asymmetric Synthesis,’ Vol.229, Springer, Berlin, 2003, pp. 1-40.
• A. Grabulosa, J. Granell, and G. Muller, Coord. Chem. Rev., 2007, 251, 25.
• J. Holz, M.-N. Gensow, O. Zayas, and A. Börner, Curr. Org. Chem., 2007, 11, 61.
• P. Štěpnička, Ed.,‘Ferrocenes: Ligands, Materials and Biomolecules,’ John Wiley&Sons, Ltd., England, 2008; R. G. Arrayás, J. Adrio, and J. C. Carretero, Angew. Chem. Int. Ed., 2006, 45, 7674.

Terms in the title (6)： 誘導体 ,  ジアステレオ選択 ,  分子内環化 ,  光学活性 ,  フェロセン ,  環