Art

J-GLOBAL ID：200902276253387707   Reference number：08A0934232

Regioselective ring opening of benzylidene acetal protecting group(s) of hexopyranoside derivatives by DIBAL-H

ヘキソピラノシド誘導体のベンジリデンアセタール保護基のDIBAL-Hによる位置選択的開環

Author (4)： TANAKA Nobuo (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1, Ridai-cho, Okayama 700-0005, JPN) ,  OGAWA Izumi (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1, Ridai-cho, Okayama 700-0005, JPN) ,  YOSHIGASE Shigeki (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1, Ridai-cho, Okayama 700-0005, JPN) ,  NOKAMI Junzo (Dep. of Applied Chemistry, Okayama Univ. of Sci., 1-1, Ridai-cho, Okayama 700-0005, JPN)
Material： Carbohydrate Research  (Carbohydr Res)
Volume： 343  Issue： 15  Page： 2675-2679  Publication year： Oct. 13, 2008 
JST Material Number： B0929A  ISSN： 0008-6215  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： regiospecific reaction ,  ring-opening reaction ,  functional group protection ,  acetal ,  *deprotection ,  solvent effect ,  reduction(reaction) ,  *pyranoside ,  hydride ,  reducing agent ,  storage ,  aliphatic chlorine compound ,  alkylbenzene
Semi thesaurus term： ベンジリデンアセタール

JST classification (1)： Glycosides  (CF10057O)

Substance index (15)： Diisobutyl aluminum hydride ,  Methylene chloride ,  Toluene ,  Methyl 2-O,3-O-dibenzyl-4-O,6-O-benzylidene-α-D-glucopyranoside ,  2-O,3-O,4-O-Tribenzylmethyl α-D-glucopyranoside ,  2-O,3-O,6-O-Tribenzyl-methyl α-D-glucopyranoside ,  Methyl 2-O,3-O-dibenzyl-4-O,6-O-benzylidene-α-D-mannopyranoside ,  Methyl-2-O,3-O,4-O-tribenzyl-α-D-mannopyranoside ,  Methyl 2-O,3-O,6-O-tribenzyl-α-D-mannopyranoside ,  Methyl 2-O,3-O-dibenzyl-4-O,6-O-benzylidene-α-D-galactopyranoside ,  Methyl 2-O,3-O,6-O-tribenzyl-α-D-galactopyranoside ,  Methyl 2-O,3-O:4-O,6-O-bis[(αR)-benzylidene]-α-D-mannopyranoside ,  Methyl 2-O,3-O-[(αS)-benzylidene]-4-O,6-O-[(αR)-benzylidene]-α-D-mannopyranoside ,  Methyl 2-O-benzyl-4-O,6-O-benzylidene-α-D-mannopyranoside ,  Methyl-3-O-benzyl-4-O,6-O-benzylidene-α-D-mannopyranoside

Terms in the title (5)： 誘導体 ,  保護基 ,  DIBAL-H ,  位置選択 ,  開環