Art

J-GLOBAL ID：200902281367485699   Reference number：08A0197223

Rhodium/Chiral Diene-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Arylmethylene Cyanoacetates

ロジウム/キラルジエン触媒によるアリールメチレンシアノアセタート類へのアリールボロン酸類の不斉1,4-付加

Author (5)： SOERGEL Sebastian (Kyoto Univ., Kyoto, JPN) ,  TOKUNAGA Norihito (Kyoto Univ., Kyoto, JPN) ,  SASAKI Keigo (Kyoto Univ., Kyoto, JPN) ,  OKAMOTO Kazuhiro (Kyoto Univ., Kyoto, JPN) ,  HAYASHI Tamio (Kyoto Univ., Kyoto, JPN)
Material： Organic Letters  (Org Lett)
Volume： 10  Issue： 4  Page： 589-592  Publication year： Feb. 21, 2008 
JST Material Number： W1171A  ISSN： 1523-7060  CODEN： ORLEF7  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *rhodium complex ,  *organorhodium compound ,  rhodium catalyst ,  ligand ,  ligand effect ,  asymmetric synthesis ,  addition reaction ,  organic boron acid ,  unsaturated carboxylic acid ,  nitrile ,  urologic active drug ,  bridged compound ,  asymmetric catalyst ,  chiral ligand
Semi thesaurus term： bridged compound ,  chiral catalyst ,  chiral ligand

JST classification (4)： Platinum family element complexes  (CE01100E) ,  Organic platinum group compound  (CF09058L) ,  Stereochemistry of organic reaction  (CF02130V) ,  Synthesis of drugs  (GV01030F)

Substance index (25)： 2,5-Dibenzyl-1β,4β-ethano-2,5-cyclohexadiene ,  (4α)-1β,8-Dimethyl-2-isobutyl-5-benzyl-8-methoxybicyclo[2.2.2]octa-2,5-diene ,  α-Cyano-4-methoxycinnamic acid methyl ester ,  (E)-α-Cyano-3-methoxybenzeneacrylic acid methyl ester ,  (E)-α-Cyano-2-methoxybenzeneacrylic acid methyl ester ,  (E)-α-Cyano-2-methylbenzeneacrylic acid methyl ester ,  (E)-α-Cyanonaphthalene-2-acrylic acid methyl ester ,  α-Cyanocinnamic acid methyl ,  (E)-α-Cyano-4-chlorobenzeneacrylic acid methyl ester ,  Phenylboronic acid ,  4-Methylphenylboronic acid ,  3-Methylphenylboronic acid ,  4-Bromophenylboronic acid ,  (3R)-2-Cyano-3-(4-methoxyphenyl)-3-phenylpropanoic acid methyl ester ,  (3R)-2-Cyano-3-(3-methoxyphenyl)-3-phenylpropanoic acid methyl ester ,  (3R)-2-Cyano-3-(2-methoxyphenyl)-3-phenylpropanoic acid methyl ester ,  (3R)-2-Cyano-3-(2-methylphenyl)-3-phenylpropanoic acid methyl ester ,  (3R)-2-Cyano-3-(2-naphthyl)-3-phenylpropanoic acid methyl ester ,  (3R)-2-Cyano-3-(4-methoxyphenyl)-3-(4-methylphenyl)propanoic acid methyl ester ,  (3S)-2-Cyano-3-(4-methoxyphenyl)-3-(3-methylphenyl)propanoic acid methyl ester ,  (3S)-2-Cyano-3-(4-methoxyphenyl)-3-(4-bromophenyl)propanoic acid methyl ester ,  (3S)-2-Cyano-3-phenyl-3-(4-methylphenyl)propanoic acid methyl ester ,  (3S)-2-Cyano-3-phenyl-3-(4-bromophenyl)propanoic acid methyl ester ,  (3S)-2-Cyano-3-phenyl-3-(4-chlorophenyl)propanoic acid methyl ester ,  Tolterodine

Terms in the title (3)： ロジウム ,  触媒 ,  アリールボロン酸類