Art

J-GLOBAL ID：200902281793389184   Reference number：04A0550461

Synthesis of optically active β-alkyl aspartate via [3,3] sigmatropic rearrangement of α-acyloxytrialkylsilane.

α-アシルオキシトリアルキルシランの[3,3]シグマトロピ転位を経る光学活性β-アルキルアスパルタートの合成

Author (7)： SAKAGUCHI K (Osaka City Univ., Osaka, JPN) ,  YAMAMOTO M (Osaka City Univ., Osaka, JPN) ,  KAWAMOTO T (Osaka City Univ., Osaka, JPN) ,  YAMADA T (Osaka City Univ., Osaka, JPN) ,  SHINADA T (Osaka City Univ., Osaka, JPN) ,  SHIMAMOTO K (Suntory Inst. Bioorganic Res., Osaka, JPN) ,  OHFUNE Y (Osaka City Univ., Osaka, JPN)
Material： Tetrahedron Letters  (Tetrahedron Lett)
Volume： 45  Issue： 30  Page： 5869-5872  Publication year： Jul. 19, 2004 
JST Material Number： E0366A  ISSN： 0040-4039  Document type： Article
Article type： 短報  Country of issue： United Kingdom (GBR)  Language： ENGLISH (EN)

Thesaurus term： *amino acid ,...

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JST classification (3)： Amino acids  (CF10070V) ,  Organosilicon compounds  (CF08030C) ,  Stereochemistry of organic reaction  (CF02130V)

Substance index (18)： (3S)-3-Hydroxyaspartic acid ,  TBOA ,  (3S)-3-Methyl-L-aspartic acid ,  (3S)-2,3-Dimethyl-L-aspartic acid ,  (3S)-β-Phenethyl-L-aspartic acid ,  (3R)-3-Methyl-L-aspartic acid ,  (3R)-2,3-Dimethyl-L-aspartic acid ,  N-(tert-Butoxycarbonyl)glycine (1S,2E)-1-(tert-butyldimethylsiloxy)-2-butenyl ester ,  N-(tert-Butoxycarbonyl)-L-alanine (1S,2E)-1-(tert-butyldimethylsiloxy)-2-butenyl ester ,  (2S,3R)-2-Amino-3-methyl-4-pentenoic acid ,  (2S,3R)-2-Amino-2,3-dimethyl-4-pentenoic acid ,  N-(tert-Butoxycarbonyl)glycine (1S,2Z)-1-(tert-butyldimethylsiloxy)-2-butenyl ester ,  N-(tert-Butoxycarbonyl)-L-alanine (1S,2Z)-1-(tert-butyldimethylsiloxy)-2-butenyl ester ,  (2S,3S)-2-Amino-3-methyl-4-pentenoic acid ,  (2S,3S)-2-Amino-2,3-dimethyl-4-pentenoic acid ,  (2S,3R)-2-(tert-Butoxycarbonylamino)-3-phenethyl-5-(tert-butyldimethylsiloxy)-4-pentenoic acid ,  (2S,3R)-2-Amino-3-phenethyl-4-pentenoic acid ,  (2S,3R)-2-(tert-Butoxycarbonylamino)-3-phenethyl-5-(tert-butyldimethylsiloxy)-4-pentenoic acid methyl ester

Terms in the title (2)： 転位 ,  光学活性