Art

J-GLOBAL ID：200902281953328241   Reference number：05A0279649

Silylene Transfer to Carbonyl Compounds and Subsequent Ireland-Claisen Rearrangements to Control Formation of Quaternary Carbon Stereocenters

カルボニル化合物へのシリレン移動と引き続いての第四炭素立体中心の形成を制御するIreland-Claisen転位

Author (2)： CALAD S A (Univ. California, California) ,  WOERPEL K A (Univ. California, California)
Material： Journal of the American Chemical Society  (J Am Chem Soc)
Volume： 127  Issue： 7  Page： 2046-2047  Publication year： Feb. 23, 2005 
JST Material Number： C0254A  ISSN： 0002-7863  CODEN： JACSAT  Document type： Article
Article type： 短報  Country of issue： United States (USA)  Language： ENGLISH (EN)

Thesaurus term： *Claisen rearrangement ,...
Semi thesaurus term： Ireland-Claisenテンイ

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JST classification (2)： Organosilicon compounds  (CF08030C) ,  Rearrangement reaction,isomerization  (CF02070E)

Substance index (26)： Isobutyric acid 3-butenyl ester ,  1,2-(Ditert-butylsilylene)cyclohexane ,  1-(3-Butenyloxy)-2-methyl-1-propenyldi-tert-butylsilanol ,  Acrylic acid benzyl ,  Methacrylic acid benzyl ,  Tiglic acid benzyl ester ,  Benzyl 2-butenoate ,  Phenyl isopropenyl ketone ,  4-Phenyl-3-buten-2-one ,  2,2-Di-tert-butyl-5-(benzyloxy)-1-oxa-2-sila-4-cyclopentene ,  2,2-Di-tert-butyl-4-methyl-5-(benzyloxy)-1-oxa-2-sila-4-cyclopentene ,  2,2-Di-tert-butyl-3,4-dimethyl-5-(benzyloxy)-1-oxa-2-sila-4-cyclopentene ,  2,2-Di-tert-butyl-3-methyl-5-ethoxy-1-oxa-2-sila-4-cyclopentene ,  2,2-Di-tert-butyl-4-methyl-5-phenyl-1-oxa-2-sila-4-cyclopentene ,  2,2-Di-tert-butyl-3-phenyl-5-methyl-1-oxa-2-sila-4-cyclopentene ,  Ethyl tiglate ,  (2S,3S)-2-Methyl-3-(hydroxydi-tert-butylsilyl)butanoic acid ethyl ester ,  Methacrylic acid allyl ,  2,2-Di-tert-butyl-4-allyl-4-methyl-1-oxa-2-silacyclopentane-5-one ,  trans-Cinnamyl tiglate ,  Tiglic acid crotyl ester ,  (3R)-2,2-Di-tert-butyl-3α,4α-dimethyl-4-[(S)-1-phenyl-2-propenyl]-1-oxa-2-silacyclopentane-5-one ,  (3R)-2,2-Di-tert-butyl-3α,4α-dimethyl-4-[(R)-1-methyl-2-propenyl]-1-oxa-2-silacyclopentane-5-one ,  (2S,3R)-2-[(R)-1-Methyl-2-propenyl]-2-methyl-1,3-butanediol ,  (4R)-2,2-Di-tert-butyl-5β-phenyl-1-oxa-2-silacyclopentane-4β-carboxylic acid benzyl ester ,  (2R)-2-[(S)-α-Hydroxybenzyl]-3-(hydroxydi-tert-butylsilyl)propionic acid benzyl ester

Terms in the title (5)： カルボニル化合物 ,  シリレン ,  炭素 ,  立体中心 ,  Ireland-Claisen転位